Judd-Ofelt analysis and energy transfer processes of Er3+ and Nd3+ doped fluoroaluminate glasses with low phosphate content
文献类型:期刊论文
作者 | Huang, Feifei; Zhang, Yu; Hu, Lili; Chen, Danping |
刊名 | opt. mater.
![]() |
出版日期 | 2014 |
卷号 | 38页码:167 |
关键词 | Fluoroaluminate glasses Energy transfer efficiency Mid-infrared emission |
通讯作者 | chen, dp (reprint author), chinese acad sci, shanghai inst opt & fine mech, key lab mat high power laser, shanghai 201800, peoples r china. |
英文摘要 | spectroscopic property and energy transfer processes of singly doped and codoped er3+ and nd3+ fluoroaluminate glasses with low phosphate content are systematically analyzed. the absorption spectra of these glasses are tested, and the judd-ofelt (j-o) and radiative parameters are discussed based on j-o theory and the parameters changes substantially because of the other codoping ions. as for nd3+: the main emission bands at 0.9 and 1.05 mu m decrease in the codoped sample under the excitation of an 800 nm laser diode from the emission spectra because the er3+: i-4(11/2) level reduces the nd3+: i-4(3/2) level effectively through the energy transfer process nd3+: f-4(3/2) -> er3+: i-4(11/2). for er3+, the emission at 1.5 mu m is restrained by codoping with nd3+ ions from the energy transfer process er3+: i-4(13/2) -> nd3+: i-4(15/2). the emission at 2.7 mu m is enhanced because the nd3+ ions deplete the lower level and exert a positive effect on the upper laser level. the microparameters of the energy transfer between the er3+ and nd3+ ions are calculated and discussed using forster-dexter theory. the energy transfer efficiencies of the nd3+: f-4(3/2) to the er3+: i-4(11/2) and the er3+: i-4(13/2) to the nd3+: i-4(15/2) are 28.8% and 74.5%, respectively. these results indicate that nd3+ can be an efficient sensitizer for er3+ to obtain mid-infrared (mid-ir),emission and the codoped er3+/nd3+ fluoroaluminate glass with low phosphate content is suitable to be used as the fiber optical gain media for 2.7 mu m laser generation. (c) 2014 elsevier b.v. all rights reserved. |
收录类别 | SCI |
语种 | 英语 |
版本 | 出版稿 |
源URL | [http://ir.siom.ac.cn/handle/181231/13368] ![]() |
专题 | 上海光学精密机械研究所_高功率激光单元技术研发中心 |
作者单位 | 1.[Huang, Feifei 2.Zhang, Yu 3.Hu, Lili 4.Chen, Danping] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China 5.[Huang, Feifei 6.Zhang, Yu] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, Feifei,Zhang, Yu,Hu, Lili,et al. Judd-Ofelt analysis and energy transfer processes of Er3+ and Nd3+ doped fluoroaluminate glasses with low phosphate content[J]. opt. mater.,2014,38:167. |
APA | Huang, Feifei,Zhang, Yu,Hu, Lili,&Chen, Danping.(2014).Judd-Ofelt analysis and energy transfer processes of Er3+ and Nd3+ doped fluoroaluminate glasses with low phosphate content.opt. mater.,38,167. |
MLA | Huang, Feifei,et al."Judd-Ofelt analysis and energy transfer processes of Er3+ and Nd3+ doped fluoroaluminate glasses with low phosphate content".opt. mater. 38(2014):167. |
入库方式: OAI收割
来源:上海光学精密机械研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。