Excitonic Relaxation and Coherent Vibrational Dynamics in Zinc Chlorin Aggregates for Artificial Photosynthetic Systems
文献类型：期刊论文
| 作者 | Han, Dongjia; Du, Juan; Kobayashi, Takayoshi; Miyatake, Tomohiro; Tamiaki, Hitoshi; Li, Yanyan; Leng, Yuxin |
| 刊名 | j. phys. chem. b
 |
| 出版日期 | 2015 |
| 卷号 | 119期号:37页码:12265 |
| 通讯作者 | du, j (reprint author), chinese acad sci, shanghai inst opt & fine mech, state key lab high field laser phys, shanghai 201800, peoples r china. |
| 英文摘要 | the excitonic relaxation and coherent vibrational dynamics in stairlike zinc chlorin aggregates prepared for mimicking chlorosome in nature have been studied simultaneously by 6.8 fs real-time vibrational laser spectroscopy. the relaxation from qexciton state to the dark nonfluorescent charge-transfer (ct) state is determined to be 850 +/- 70 fs. the spectral distribution of the molecular vibrational amplitude has been discussed in terms of the difference in the equilibrium positions of potential curves between the ground state and the excited state. since the displacement in the coordinate space from the potential minimum of the ground state to that of the excited states is small, coherent oscillations generated by the impulsive excitation are strongest where the slope of the excitonic resonance is largest. consequently, the probe wavelength dependence of the amplitude modulation follows the first derivative of the excitonic resonance, and pi phase jump has been observed. excitonic transition energy modulation caused by the coherent molecular vibrations has also been studied, and the vibrational mode with a low frequency of 146 cm(-1) is found to play a dominating role in the transition energy shift effect. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 版本 | 出版稿 |
| 源URL | [http://ir.siom.ac.cn/handle/181231/14090]  |
| 专题 | 上海光学精密机械研究所_强场激光物理国家重点实验室 |
| 作者单位 | 1.[Han, Dongjia 2.Du, Juan 3.Li, Yanyan 4.Leng, Yuxin] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, State Key Lab High Field Laser Phys, Shanghai 201800, Peoples R China 5.[Kobayashi, Takayoshi] Univ Electrocommun, Adv Ultrafast Laser Res Ctr, Chofu, Tokyo 1828585, Japan 6.[Kobayashi, Takayoshi] JST, CREST, Chiyoda Ku, Tokyo 1020076, Japan 7.[Miyatake, Tomohiro] Ryukoku Univ, Dept Chem Mat, Otsu, Shiga 5202194, Japan 8.[Tamiaki, Hitoshi] Ritsumeikan Univ, Dept Biosci & Biotechnol, Kusatsu, Shiga 5258577, Japan 9.[Leng, Yuxin] Shanghai Jiao Tong Univ, FSA Collaborat Innovat Ctr, Shanghai 200240, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Dongjia,Du, Juan,Kobayashi, Takayoshi,et al. Excitonic Relaxation and Coherent Vibrational Dynamics in Zinc Chlorin Aggregates for Artificial Photosynthetic Systems[J]. j. phys. chem. b,2015,119(37):12265. |
| APA | Han, Dongjia.,Du, Juan.,Kobayashi, Takayoshi.,Miyatake, Tomohiro.,Tamiaki, Hitoshi.,...&Leng, Yuxin.(2015).Excitonic Relaxation and Coherent Vibrational Dynamics in Zinc Chlorin Aggregates for Artificial Photosynthetic Systems.j. phys. chem. b,119(37),12265. |
| MLA | Han, Dongjia,et al."Excitonic Relaxation and Coherent Vibrational Dynamics in Zinc Chlorin Aggregates for Artificial Photosynthetic Systems".j. phys. chem. b 119.37(2015):12265. |
入库方式： OAI收割
来源：上海光学精密机械研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。