Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics
文献类型:期刊论文
作者 | Hanlon, Damien; Backes, Claudia; Doherty, Evie; Cucinotta, Clotilde S.; Berner, Nina C.; Boland, Conor; Lee, Kangho; Harvey, Andrew; Lynch, Peter; Gholamvand, Zahra |
刊名 | nat. commun.
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出版日期 | 2015 |
卷号 | 6页码:8563 |
通讯作者 | coleman, jn (reprint author), trinity coll dublin, sch phys, dublin 2, ireland. |
英文摘要 | few-layer black phosphorus (bp) is a new two-dimensional material which is of great interest for applications, mainly in electronics. however, its lack of environmental stability severely limits its synthesis and processing. here we demonstrate that high-quality, few-layer bp nanosheets, with controllable size and observable photoluminescence, can be produced in large quantities by liquid phase exfoliation under ambient conditions in solvents such as n-cyclohexyl-2-pyrrolidone (chp). nanosheets are surprisingly stable in chp, probably due to the solvation shell protecting the nanosheets from reacting with water or oxygen. experiments, supported by simulations, show reactions to occur only at the nanosheet edge, with the rate and extent of the reaction dependent on the water/oxygen content. we demonstrate that liquid-exfoliated bp nanosheets are potentially useful in a range of applications from ultrafast saturable absorbers to gas sensors to fillers for composite reinforcement. |
收录类别 | SCI |
语种 | 英语 |
版本 | 出版稿 |
源URL | [http://ir.siom.ac.cn/handle/181231/14263] ![]() |
专题 | 上海光学精密机械研究所_中科院强激光材料重点实验室 |
作者单位 | 1.[Hanlon, Damien 2.Backes, Claudia 3.Doherty, Evie 4.Cucinotta, Clotilde S. 5.Berner, Nina C. 6.Boland, Conor 7.Lee, Kangho 8.Harvey, Andrew 9.Lynch, Peter 10.Gholamvand, Zahra |
推荐引用方式 GB/T 7714 | Hanlon, Damien,Backes, Claudia,Doherty, Evie,et al. Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics[J]. nat. commun.,2015,6:8563. |
APA | Hanlon, Damien.,Backes, Claudia.,Doherty, Evie.,Cucinotta, Clotilde S..,Berner, Nina C..,...&McEvoy.(2015).Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics.nat. commun.,6,8563. |
MLA | Hanlon, Damien,et al."Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics".nat. commun. 6(2015):8563. |
入库方式: OAI收割
来源:上海光学精密机械研究所
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