Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis
文献类型：期刊论文
| 作者 | Lv, Qiunan1,2 ; Li, Lu1,2,3; Li, Xiaosen1,2; Chen, Zhaoyang1,2
|
| 刊名 | energy & fuels
 |
| 出版日期 | 2015-09-01 |
| 卷号 | 29期号:9页码:6104-6110 |
| 英文摘要 | the kinetics of the formation of cyclopentane (cp) + methane (ch4) hydrates are studied to find the optimum condition for the rapid hydrate formation under the submarine condition (nacl mass fraction of 0.035, around 277.15 k and 12 mpa). the influences of the cp/liquid phase volume ratio and the volume of the liquid phase on the amount of gas uptake and ch4 consumption rate are determined. the results show that the high volume ratio of cp/liquid phase is favorable for the rapid formation of cp + ch4 hydrates. there is an optimal ratio of the liquid phase volume for obtaining the highest gas consumption. raman spectrum analyses for cp + ch4 hydrates are carried out to examine the hydrate structure and guest molecule occupation. the results show that cp mainly occupies the large cavities (5(12)6(4)) and ch4 is encapsulated in the small cavities (5(12)) of the structure ii hydrates. when the volume ratio of the cp/liquid phase is 0.05, cp with ch4 also occupies the large cavities (5(12)6(4)). |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | energy & fuels ; engineering, chemical |
| 研究领域[WOS] | energy & fuels ; engineering |
| 关键词[WOS] | binary clathrate hydrate ; carbon-dioxide capture ; production behavior ; phase-equilibrium ; guest molecules ; gas-production ; natural-gas ; stimulation ; mixture ; crystallization |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000363068200061 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10879]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Qiunan,Li, Lu,Li, Xiaosen,et al. Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis[J]. energy & fuels,2015,29(9):6104-6110. |
| APA | Lv, Qiunan,Li, Lu,Li, Xiaosen,&Chen, Zhaoyang.(2015).Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis.energy & fuels,29(9),6104-6110. |
| MLA | Lv, Qiunan,et al."Formation Kinetics of Cyclopentane plus Methane Hydrates in Brine Water Systems and Raman Spectroscopic Analysis".energy & fuels 29.9(2015):6104-6110. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。