中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone

文献类型:期刊论文

作者Xu, Zhiping1; Li, Wenzhi2; Du, Zhijie2; Wu, Hao2; Jameel, Hasan3; Chang, Hou-min3; Ma, Longlong4
刊名bioresource technology
出版日期2015-12-01
卷号198页码:764-771
关键词Furfural Xylose Corn stalk PTSA-POM catalyst gamma-Valerolactone
英文摘要a novel solid acid catalyst was prepared by the copolymerization of p-toluenesulfonic acid and paraformaldehyde and then characterized by ft-ir, tg/dtg, hrtem and n-2-bet. furfural was successfully produced by the dehydration of xylose and xylan using the novel catalyst in gamma-valerolactone. this investigation focused on effects of various reaction conditions including solvent, acid catalyst, reaction temperature, residence time, water concentration, xylose loading and catalyst dosage on the dehydration of xylose to furfural. it was found that the solid catalyst displayed extremely high activity for furfural production. 80.4% furfural yield with 98.8% xylose conversion was achieved at 170 degrees c for 10 min. the catalyst could be recycled at least five times without significant loss of activity. furthermore, 83.5% furfural yield and 19.5% hmf yield were obtained from raw corn stalk under more severe conditions (190 degrees c for 100 min). (c) 2015 elsevier ltd. all rights reserved.
WOS标题词science & technology ; life sciences & biomedicine ; technology
类目[WOS]agricultural engineering ; biotechnology & applied microbiology ; energy & fuels
研究领域[WOS]agriculture ; biotechnology & applied microbiology ; energy & fuels
关键词[WOS]d-xylose ; ionic liquid ; lignocellulosic biomass ; selective conversion ; sugar production ; levulinic acid ; maleic-acid ; solid acids ; hemicellulose ; xylan
收录类别SCI
语种英语
WOS记录号WOS:000363487500097
源URL[http://ir.giec.ac.cn/handle/344007/10883]  
专题中国科学院广州能源研究所
作者单位1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
2.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China
3.N Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Xu, Zhiping,Li, Wenzhi,Du, Zhijie,et al. Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone[J]. bioresource technology,2015,198:764-771.
APA Xu, Zhiping.,Li, Wenzhi.,Du, Zhijie.,Wu, Hao.,Jameel, Hasan.,...&Ma, Longlong.(2015).Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone.bioresource technology,198,764-771.
MLA Xu, Zhiping,et al."Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in gamma-valerolactone".bioresource technology 198(2015):764-771.

入库方式: OAI收割

来源:广州能源研究所

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