Hydrate-based hydrogen purification from simulated syngas with synergic additives
文献类型：期刊论文
| 作者 | Xia, Zhiming1,2; Li, Xiaosen1,2; Chen, Zhaoyang1,2; Yan, Kefeng1,2; Xu, Chungang1,2; Cai, Jing1,2 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2016-01-30 |
| 卷号 | 41期号:4页码:2649-2659 |
| 关键词 | Syngas Purification Synergic additive Gas hydrate Hydrogen |
| 英文摘要 | hydrated-based separation process has recently raised as a novel technology for hydrogen (h-2) purification from mixture gases containing carbon dioxide (co2). however, the practical application requires suitable hydrate formation condition, hydrate formation rate, gas selectivity, gas storage capacity and so on. this work presents the effect of synergic additives on the hydrate-based syngas purification process based on the thermodynamic, kinetic, purification characteristic studies as well as microcosmic structure analysis. the synergic additives comprise traditional hydrate promoter (tetra-n-butyl ammonium bromide, tbab) and gas solvent (dimethyl sulfoxide, dmso). 40.2 mol% co2/h-2 binary mixtures were selected as the simulated syngas. the results show that the synergic additives (tbab-dmso) can reduce the equilibrium hydrate formation pressure of the simulated syngas by 80%. compared to single tbab for the hydrate-based purification process, the synergic additives could improve the gas consumption rate of the unit system, gas storage capability and gas selectivity by about 32%, 105% and 51% respectively, and decrease the loss ratio of h-2 by 1.45%. the raman analysis reveals that the simulated syngas forms semiclathrate framework with tbab-dmso. dmso only performs as a gas solvent during the gas dissolution and diffusion process, and not participates in the hydrate framework formation. copyright (c) 2015, hydrogen energy publications, llc. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | pre-combustion capture ; fixed-bed reactor ; carbon-dioxide capture ; butyl ammonium bromide ; fuel gas-mixture ; co2 capture ; clathrate hydrate ; phase-equilibrium ; methane separation ; research progress |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000370306300053 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/11120]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Zhiming,Li, Xiaosen,Chen, Zhaoyang,et al. Hydrate-based hydrogen purification from simulated syngas with synergic additives[J]. international journal of hydrogen energy,2016,41(4):2649-2659. |
| APA | Xia, Zhiming,Li, Xiaosen,Chen, Zhaoyang,Yan, Kefeng,Xu, Chungang,&Cai, Jing.(2016).Hydrate-based hydrogen purification from simulated syngas with synergic additives.international journal of hydrogen energy,41(4),2649-2659. |
| MLA | Xia, Zhiming,et al."Hydrate-based hydrogen purification from simulated syngas with synergic additives".international journal of hydrogen energy 41.4(2016):2649-2659. |
入库方式： OAI收割
来源：广州能源研究所
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