Continuous pyrolysis and catalytic upgrading of corncob hydrolysis residue in the combined system of auger reactor and downstream fixed-bed reactor
文献类型：期刊论文
| 作者 | Li, Yuping1; Li, Bosong1,2; Zhang, Xinghua1; Chen, Lungang1; Zhang, Qi1; Wang, Tiejun1; Ma, Longlong1 |
| 刊名 | energy conversion and management
 |
| 出版日期 | 2016-08-15 |
| 卷号 | 122页码:1-9 |
| 关键词 | Pyrolysis Ex situ catalysis Bio-oil upgrading HZSM-5 Mono-phenols and aromatics |
| 英文摘要 | continuous pyrolysis of corncob hydrolysis residue, coupled with ex situ catalytic upgrading of the pyrolysis vapor, was investigated in the combined system of an auger reactor and a downstream fixed-bed reactor. the effect of the zeolite catalyst, usy (ultrastable y) and hzsm-5 (si/al=25, 38) and catalytic temperature on the raw bio-oil upgrading were discussed. the results showed the strong acidity of porous zeolite was essential for catalytic deoxygenation during upgrading pyrolysis vapor. hzsm-5 (25), with the strong acidity and acidic sites, had favored the deoxygenation conversion of carbonyl/carboxyl-containing oxygenates in the pyrolysis vapor, which decreased its content to 2.3 area% via the gc-ms analysis of the upgraded bio-oil. mono-phenols (phenol and alkylphenols) were enhanced to 53.2 area% over hzsm-5 (25), as compared with that of 17.3 area% during non-catalysis process. the addition of ex situ catalytic upgrading had improved the quality of organic big-oil at the expense of its yield. coke formation on the strong acidic sites by condensation of intermediates is detrimental to organic bio-oil yield. the increase of catalysis temperature at the fixed-bed reactor decreased oxygenate compounds to 7.1 area%, 23 area% and 1.9 area% at 450 degrees c, 550 degrees c and 650 degrees c, respectively, with 0.75 s of vapor residence time. the tg/dtg/dsc characterization of the used hzsm-5 (25) implied that the coke had deposited on the surface of hzsm-5 (25), which could be removed by combustion to recover its activity. (c) 2016 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | thermodynamics ; energy & fuels ; mechanics ; physics, nuclear |
| 研究领域[WOS] | thermodynamics ; energy & fuels ; mechanics ; physics |
| 关键词[WOS] | modified zsm-5 ; co-pyrolysis ; douglas-fir ; bio-oil ; biomass ; lignin ; vapor ; wood ; zeolite ; methanol |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000379632600001 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/11782]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.CATAS, Trop Energy & Ecol Res Ctr, Guangzhou Expt Stn, Guangzhou 510140, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yuping,Li, Bosong,Zhang, Xinghua,et al. Continuous pyrolysis and catalytic upgrading of corncob hydrolysis residue in the combined system of auger reactor and downstream fixed-bed reactor[J]. energy conversion and management,2016,122:1-9. |
| APA | Li, Yuping.,Li, Bosong.,Zhang, Xinghua.,Chen, Lungang.,Zhang, Qi.,...&Ma, Longlong.(2016).Continuous pyrolysis and catalytic upgrading of corncob hydrolysis residue in the combined system of auger reactor and downstream fixed-bed reactor.energy conversion and management,122,1-9. |
| MLA | Li, Yuping,et al."Continuous pyrolysis and catalytic upgrading of corncob hydrolysis residue in the combined system of auger reactor and downstream fixed-bed reactor".energy conversion and management 122(2016):1-9. |
入库方式： OAI收割
来源：广州能源研究所
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