Determination of six sulfonylurea herbicides in environmental water samples by magnetic solid-phase extraction using multi-walled carbon nanotubes as adsorbents coupled with high-performance liquid chromatography
文献类型：期刊论文
| 作者 | Ma, JP; Jiang, LH; Wu, GG; Xia, Y; Lu, WH; Li, JH ; Chen, LX
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| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2016-09-30 |
| 卷号 | 1466页码:12-20 |
| 关键词 | Sulfonylurea herbicides Magnetic solid-phase extraction Multi-walled carbon nanotubes Water samples High-performance liquid chromatography |
| ISSN号 | 0021-9673 |
| 产权排序 | [Ma, Jiping; Jiang, Lianhua; Wu, Gege; Xia, Yan] Qingdao Technol Univ, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China; [Lu, Wenhui; Li, Jinhua; Chen, Lingxin] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Shandong Prov Key Lab Coastal Environm Proc, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China |
| 通讯作者 | Ma, JP (reprint author), Qingdao Technol Univ, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China. ; Chen, LX (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Shandong Prov Key Lab Coastal Environm Proc, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China. Email:majiping2012@163.com ; lxchen@yic.ac.cn |
| 英文摘要 | Magnetic solid-phase extraction (MSPE) using magnetic multi-walled carbon nanotubes (mag-MWCNTs) as adsorbents, coupled with high-performance liquid chromatography-diode-array detector (HPLC-DAD), was developed for the simultaneous separation and determination of six types of sulfonylurea herbicides (SUs) in environmental water samples. Several variables affecting MSPE efficiency were systematically investigated, including the type and volume of desorption solvent, sample solution pH, salt concentration, amount of mag-MWCNTs, and extraction and desorption time. Response surface was employed to assist in the MSPE optimization. Under optimized conditions, excellent linearity was achieved in the range of 0.05-5.0 mu g/L for all six SUs, with coefficients of correlation r > 0.9994, and preconcentration factors ranging from 178 to 210. Limits of detection and quantification were 0.01-0.04 mu g/L and 0.03-0.13 mu g/L, respectively. The intra-day and inter-day precision (relative standard deviations, n = 6, %) at three spiked levels were 2.0-11.0% and 2.1-12.9% in terms of peak area, respectively. The method recoveries at three fortified concentrations were obtained within 76.7-106.9% for reservoir water samples and 78.2-105.4% for tap water samples. The developed MSPE-HPLC method demonstrated high sensitivity, repeatability, simplicity, rapidity, and excellent practical applicability. (C) 2016 Elsevier B.V. All rights reserved. |
| 研究领域[WOS] | Biochemistry & Molecular Biology ; Chemistry |
| 关键词[WOS] | MOLECULARLY IMPRINTED POLYMER ; MASS-SPECTROMETRY ; PHTHALATE-ESTERS ; SOIL SAMPLES ; PESTICIDES ; SILICA |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000384869000002 |
| 源URL | [http://ir.yic.ac.cn/handle/133337/17477]  |
| 专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 |
| 推荐引用方式 GB/T 7714 | Ma, JP,Jiang, LH,Wu, GG,et al. Determination of six sulfonylurea herbicides in environmental water samples by magnetic solid-phase extraction using multi-walled carbon nanotubes as adsorbents coupled with high-performance liquid chromatography[J]. JOURNAL OF CHROMATOGRAPHY A,2016,1466:12-20. |
| APA | Ma, JP.,Jiang, LH.,Wu, GG.,Xia, Y.,Lu, WH.,...&Chen, LX.(2016).Determination of six sulfonylurea herbicides in environmental water samples by magnetic solid-phase extraction using multi-walled carbon nanotubes as adsorbents coupled with high-performance liquid chromatography.JOURNAL OF CHROMATOGRAPHY A,1466,12-20. |
| MLA | Ma, JP,et al."Determination of six sulfonylurea herbicides in environmental water samples by magnetic solid-phase extraction using multi-walled carbon nanotubes as adsorbents coupled with high-performance liquid chromatography".JOURNAL OF CHROMATOGRAPHY A 1466(2016):12-20. |
入库方式： OAI收割
来源：烟台海岸带研究所
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