Insight into the formation of the tert-butyl cation confined inside H-ZSM-5 zeolite from NMR spectroscopy and DFT calculations
文献类型：期刊论文
| 作者 | Huang, Mengdi1,2; Wang, Qiang1; Yi, Xianfeng1,2; Chu, Yueying1; Dai, Weili3; Li, Landong3; Zheng, Anmin1; Deng, Feng1 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2016 |
| 卷号 | 52期号:70页码:10606-10608 |
| 英文摘要 | Solid-state NMR experiments and DFT calculations have been carried out to determine the complex structures of coadsorbed C-13-labeled tert-butanol and NH3 in acidic H-ZSM-5 zeolite. It is found, besides the physically adsorbed tert-butanol/NH4+ complex on Bronsted acid sites, the tert-butylamine cation is formed as well, confirming the presence of the tert-butyl cation confined in zeolite channels. Furthermore, C-13-Al-27 double-resonance solid-state NMR spectroscopy is adopted to determine the host/guest interaction between the carbocation and the zeolite framework. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CONVERSION ; IDENTIFICATION ; DEHYDRATION ; CHEMISTRY ; ALCOHOLS ; CRACKING ; OLEFINS ; ION ; H-2 ; HY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000382121000002 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/9575]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Nankai Univ, Minist Educ, Collaborat Innovat Ctr Chem Sci & Engn, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Mengdi,Wang, Qiang,Yi, Xianfeng,et al. Insight into the formation of the tert-butyl cation confined inside H-ZSM-5 zeolite from NMR spectroscopy and DFT calculations[J]. CHEMICAL COMMUNICATIONS,2016,52(70):10606-10608. |
| APA | Huang, Mengdi.,Wang, Qiang.,Yi, Xianfeng.,Chu, Yueying.,Dai, Weili.,...&Deng, Feng.(2016).Insight into the formation of the tert-butyl cation confined inside H-ZSM-5 zeolite from NMR spectroscopy and DFT calculations.CHEMICAL COMMUNICATIONS,52(70),10606-10608. |
| MLA | Huang, Mengdi,et al."Insight into the formation of the tert-butyl cation confined inside H-ZSM-5 zeolite from NMR spectroscopy and DFT calculations".CHEMICAL COMMUNICATIONS 52.70(2016):10606-10608. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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