Unravelling the Efficient Photocatalytic Activity of Boron-induced Ti3+ Species in the Surface Layer of TiO2
文献类型：期刊论文
| 作者 | Feng, Ningdong1; Liu, Fen1; Huang, Min1; Zheng, Anmin1; Wang, Qiang1; Chen, Tiehong2; Cao, Gengyu1; Xu, Jun1; Fan, Jie3,4; Deng, Feng1 |
| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2016-10-06 |
| 卷号 | 6 |
| 英文摘要 | Ti3(+) species are highly unstable in air owing to their facile oxidation into Ti4(+) species, and thus they cannot concentrate in the surface layer of TiO2 but are mainly present in its bulk. We report generation of abundant and stable Ti3(+) species in the surface layer of TiO2 by boron doping for efficient utilization of solar irradiation. The resultant photocatalysts (denoted as B-TiO2-x) exhibit extremely high and stable solar-driven photocatalytic activity toward hydrogen production. The origin of the solar-light activity enhancement in the B-TiO2-x photocatalysts has been thoroughly investigated by various experimental techniques and density functional theory (DFT) calculations. The unique structure invoked by presence of sufficient interstitial boron atoms can lead to substantial variations in density of states of B-TiO2-x, which not only significantly narrow the band gap of TiO2 to improve its visible-light absorption, but also promote the photogenerated electron mobility to enhance its solar-light photocatalytic activity. |
| WOS标题词 | Science & Technology |
| 类目[WOS] | Multidisciplinary Sciences |
| 研究领域[WOS] | Science & Technology - Other Topics |
| 关键词[WOS] | VISIBLE-LIGHT PHOTOCATALYSIS ; QUANTUM-SIZED TIO2 ; METAL-ION DOPANTS ; ANATASE TIO2 ; DOPED TIO2 ; WATER ; ABSORPTION ; XPS ; NANOPARTICLES ; ARRAYS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000384764600001 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/9595]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Natl Ctr Magnet Resonance Wuhan, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 2.Nankai Univ, Dept Chem Mat, Key Lab Funct Polymer Mat MOE, Tianjin 300071, Peoples R China 3.Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310027, Zhejiang, Peoples R China 4.Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Ningdong,Liu, Fen,Huang, Min,et al. Unravelling the Efficient Photocatalytic Activity of Boron-induced Ti3+ Species in the Surface Layer of TiO2[J]. SCIENTIFIC REPORTS,2016,6. |
| APA | Feng, Ningdong.,Liu, Fen.,Huang, Min.,Zheng, Anmin.,Wang, Qiang.,...&Deng, Feng.(2016).Unravelling the Efficient Photocatalytic Activity of Boron-induced Ti3+ Species in the Surface Layer of TiO2.SCIENTIFIC REPORTS,6. |
| MLA | Feng, Ningdong,et al."Unravelling the Efficient Photocatalytic Activity of Boron-induced Ti3+ Species in the Surface Layer of TiO2".SCIENTIFIC REPORTS 6(2016). |
入库方式： OAI收割
来源：武汉物理与数学研究所
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