A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines
文献类型：期刊论文
| 作者 | Shi, Ji-Long1,2; Zhang, Xiao-Feng1,2; Wang, Hui-Juan3; Li, Fa-Bao1,2; Zhong, Xin-Xin1,2; Liu, Chun-Xiang1,2; Liu, Li1,2; Liu, Chao-Yang3; Qin, Hai-Mei4; Huang, Yong-Shun5 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2016-09-02 |
| 卷号 | 81期号:17页码:7662-7674 |
| 英文摘要 | Thermal reaction of [60]fullerene with various arylmethanamines in the presence of aromatic aldehydes under air conditions afforded a series of rare 2,5-diaryl fulleropyrrolidines. Intriguingly, the obtained fulleropyrrolidines exhibited different stereoselectivity. N-unsubstituted arylmethanamines exclusively produced 2,5-diaryl fulleropyrrolidines as cis isomers, while N-substituted arylmethanamines with rare exceptions always gave 2,5-diaryl fulleropyrrolidines as trans isomers. Theoretical calculations at the level of B3LYP/6-31G (d,p) were employed to elucidate the stereoselectivity of N-substituted 2,5-diaryl fulleropyrrolidines as trans isomers by investigating the transition-state structures of different cycloaddition pathways. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ONE-STEP REACTION ; AMINO-ACID ESTERS ; FERRIC PERCHLORATE ; 1,3-DIPOLAR CYCLOADDITION ; AZOMETHINE YLIDES ; BUCKMINSTERFULLERENE C-60 ; ADDITION-REACTIONS ; TERTIARY-AMINES ; FULLERENE ; DERIVATIVES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000382713800036 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/9590]  |
| 专题 | 武汉物理与数学研究所_高技术创新与发展中心 |
| 作者单位 | 1.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, Wuhan 430062, Peoples R China 2.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Xiamen Univ, Coll Chem & Chem Engn, Fujian Prov Key Lab Theoret & Computat Chem, Xiamen 361005, Peoples R China 5.Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA |
| 推荐引用方式 GB/T 7714 | Shi, Ji-Long,Zhang, Xiao-Feng,Wang, Hui-Juan,et al. A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(17):7662-7674. |
| APA | Shi, Ji-Long.,Zhang, Xiao-Feng.,Wang, Hui-Juan.,Li, Fa-Bao.,Zhong, Xin-Xin.,...&Huang, Yong-Shun.(2016).A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines.JOURNAL OF ORGANIC CHEMISTRY,81(17),7662-7674. |
| MLA | Shi, Ji-Long,et al."A Protocol for the Preparation of 2,5-Diaryl Fulleropyrrolidines: Thermal Reaction of [60]Fullerene with Aromatic Aldehydes and Arylmethanamines".JOURNAL OF ORGANIC CHEMISTRY 81.17(2016):7662-7674. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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