Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides
文献类型：期刊论文
| 作者 | Yue, Hui-Lan1,2; Klussmann, Martin1 |
| 刊名 | synlett
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 27期号:17页码:2505-2509 |
| 关键词 | addition homogeneous catalysis oxygenations peroxides radical reaction sulfoxides |
| 英文摘要 | an oxidative variant of the thiol-ene reaction has been developed, achieving the direct addition of thiols to olefins to form sulfoxides. the reaction uses tert-butyl hydroperoxide as oxidant and methanesulfonic acid as catalyst. the latter is believed to catalyze the oxidation of the intermediate sulfide to the sulfoxide. no special precautions are necessary to exclude oxygen, yet the products are formed without oxidation at the -position. styrenes, acrylic acid derivatives, alkynes, and thiophenols gave the highest yields, while aliphatic olefins and thiols were less effective. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | sulfenate anions ; beta-hydroxysulfides ; enantioenriched sulfoxides ; pummerer reaction ; aryl sulfoxides ; sulfur ; arylation ; chemistry ; alkenes ; pharmacophore |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000386125700020 |
| 源URL | [http://ir.nwipb.ac.cn/handle/363003/6407]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 作者单位 | 1.Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45479 Mulheim, Germany 2.Chinese Acad Sci, Key Lab Tibetan Med Res, Northwest Inst Plateau Biol, Xining 810001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yue, Hui-Lan,Klussmann, Martin. Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides[J]. synlett,2016,27(17):2505-2509. |
| APA | Yue, Hui-Lan,&Klussmann, Martin.(2016).Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides.synlett,27(17),2505-2509. |
| MLA | Yue, Hui-Lan,et al."Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides".synlett 27.17(2016):2505-2509. |
入库方式： OAI收割
来源：西北高原生物研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。