Fabrication and properties of a novel superabsorbent composite based on coco peat and poly (acrylic acid) cross-linked trimethylolpropane trimaleate under ultraviolet irradiation
文献类型:期刊论文
作者 | Su, Xiaoyu1; Bai, Bo1; Xu, Xiaohui1; Ding, Chenxu2; Wang, Honglun2; Suo, Yourui2 |
刊名 | polymers for advanced technologies
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出版日期 | 2016-09-01 |
卷号 | 27期号:9页码:1179-1190 |
关键词 | coco peat cellulose superabsorbent composite water absorbency loading and releasing of urea |
英文摘要 | a series of novel poly(acrylic acid)/coco peat (paa/cp) superabsorbent composites were prepared via the ultraviolet irradiation copolymerization of acrylic acid monomer (paa) and coco peat cellulose (cp) in the presence of the cross-linker trimethylolpropane trimaleate. the physico-chemical structures of obtained paa/cp were characterized by fourier transform infrared spectroscopy, thermogravimetry/derivative thermogravimetry, x-ray diffraction, and scanning electron microscopy, respectively. the critical parameters of affecting the water absorbency of paa/cp, including the cross-linker level, amount of cp and reaction time, were studied in detailed. the experimental results showed that the paa/cp samples exhibited the maximum swelling value of 523.09g/g in distilled water and 40.52g/g in 0.9wt % nacl solution. the swelling behaviors of paa/cp were significantly relied on the concentration of salt solution and the ph of external solution. the effect of ions species on the swelling performance was in the order: na+>ca2+>fe3+ , and in ph 2.2 and 7.2 aqueous solutions paa/cp composites displayed better ph-responsiveness and reversible on-off switching characteristics. urea, as an agrochemical model, was loaded into paa/cp substrate to supply with nitrogen nutrient. the test of their loading and releasing diffusion performance of urea suggested that the urea loading percentage of paa/cp was remarkably dependent on the concentration of aqueous urea solutions and the release of urea from loaded paa/cp samples in water followed a non-fickian mechanism. owing to their considerable good water absorption capacity, slow urea release, economical and environment-friendly merits, paa/cp composites could be exploited for the agriculture applications. copyright (c) 2016 john wiley & sons, ltd. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | polymer science |
研究领域[WOS] | polymer science |
关键词[WOS] | swelling behaviors ; graft-copolymerization ; controlled-release ; sodium alginate ; aqueous-media ; hydrogels ; ph ; cellulose ; nanocomposites ; methacrylate |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000380946700006 |
源URL | [http://ir.nwipb.ac.cn/handle/363003/6459] ![]() |
专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
作者单位 | 1.Changan Univ, Coll Environm Sci & Engn, Xian 710054, Peoples R China 2.Chinese Acad Sci, Northwest Plateau Inst Biol, Key Lab Tibetan Med Res, Xining 810001, Peoples R China |
推荐引用方式 GB/T 7714 | Su, Xiaoyu,Bai, Bo,Xu, Xiaohui,et al. Fabrication and properties of a novel superabsorbent composite based on coco peat and poly (acrylic acid) cross-linked trimethylolpropane trimaleate under ultraviolet irradiation[J]. polymers for advanced technologies,2016,27(9):1179-1190. |
APA | Su, Xiaoyu,Bai, Bo,Xu, Xiaohui,Ding, Chenxu,Wang, Honglun,&Suo, Yourui.(2016).Fabrication and properties of a novel superabsorbent composite based on coco peat and poly (acrylic acid) cross-linked trimethylolpropane trimaleate under ultraviolet irradiation.polymers for advanced technologies,27(9),1179-1190. |
MLA | Su, Xiaoyu,et al."Fabrication and properties of a novel superabsorbent composite based on coco peat and poly (acrylic acid) cross-linked trimethylolpropane trimaleate under ultraviolet irradiation".polymers for advanced technologies 27.9(2016):1179-1190. |
入库方式: OAI收割
来源:西北高原生物研究所
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