Polarity-reversal-producing phase transfer of hydrophilic silver nanoclusters capped by a hyperbranched polymer from water to nonpolar organic solvents
文献类型：期刊论文
| 作者 | Qu, Fei1,2; Niu, Shuwen1,2; You, Jinmao1,2,3 |
| 刊名 | journal of applied polymer science
 |
| 出版日期 | 2016-03-15 |
| 卷号 | 133期号:11 |
| 关键词 | nanoparticles nanowires and nanocrystals phase behavior polyelectrolytes spectroscopy |
| 英文摘要 | hyperbranched poly(ethylene imine) (pei)-capped ag nanoclusters, synthesized starting from an aqueous environment, dispersed well in water and most polar organic solvents. however, with the addition of 1,4-dioxane, the pei-capped ag nanoclusters could be separated completely to obtain hydrophilic and hydrophobic ag nanoclusters. through this facile method, the successful phase transfer of pei-capped ag nanoclusters from the aqueous phase to the nonpolar organic phase, such as from water to carbon tetrachloride, chloroform, and methylene bichloride, was easily realized. the polarity reversal of ag nanoclusters were considered to be associated with the conformational change of pei on the basis of the hydrophobic methylene groups of polymer backbone facing the external side or internal side, and this polarity reversal was irreversible. moreover, peis with higher molecular weights showed a higher efficiency of phase transfer of the ag nanoclusters. (c) 2015 wiley periodicals, inc. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | ag nanoclusters ; gold nanoclusters ; aqueous-solution ; selective detection ; fluorescent ; clusters ; ions |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000367911400025 |
| 源URL | [http://ir.nwipb.ac.cn/handle/363003/6504]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 作者单位 | 1.Qufu Normal Univ, Key Lab Life Organ Anal, Qufu 273165, Shandong, Peoples R China 2.Qufu Normal Univ, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Shandong, Peoples R China 3.Chinese Acad Sci, Northwest Inst Plateau Biol, Xining 810001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qu, Fei,Niu, Shuwen,You, Jinmao. Polarity-reversal-producing phase transfer of hydrophilic silver nanoclusters capped by a hyperbranched polymer from water to nonpolar organic solvents[J]. journal of applied polymer science,2016,133(11). |
| APA | Qu, Fei,Niu, Shuwen,&You, Jinmao.(2016).Polarity-reversal-producing phase transfer of hydrophilic silver nanoclusters capped by a hyperbranched polymer from water to nonpolar organic solvents.journal of applied polymer science,133(11). |
| MLA | Qu, Fei,et al."Polarity-reversal-producing phase transfer of hydrophilic silver nanoclusters capped by a hyperbranched polymer from water to nonpolar organic solvents".journal of applied polymer science 133.11(2016). |
入库方式： OAI收割
来源：西北高原生物研究所
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