Enantioselective Organocatalytic Transfer Hydrogenation of 1,2-Dihydroquinoline through Formation of Aza-o-xylylene
文献类型：期刊论文
| 作者 | Li, Guangxun; Liu, Hongxin; Lv, Gang; Wang, Yingwei; Fu, Qingquan; Tang, Zhuo |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:17页码:4125-4127 |
| 关键词 | ASYMMETRIC TRANSFER HYDROGENATION METHIDE IMINE GENERATION FLASH VACUUM PYROLYSIS DIELS-ALDER REACTION BRONSTED ACID 6-AMINO-4-PHENYLTETRAHYDROQUINOLINE DERIVATIVES HANTZSCH ESTERS DEAROMATIZATION QUINOLINES RECEPTOR |
| 产权排序 | 1 |
| 通讯作者 | Li, GX (reprint author), Chinese Acad Sci, Nat Prod Res Ctr, Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | A new way of forming the aza-o-xylylene with easily accessible 1,2-dihydroquinolines as precursor has been developed. The presence of an electron-donating group at the proper position of 1,2-clihydroquinoline was crucial for protonation of the alkene through dearomatization with a simple Bremsted acid. The in situ forming reactive intermediate was trapped with Hantzsch ester to afford tetrahydroquinolines in excellent yield and enantioselectivity. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Organic |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27569]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Li, Guangxun,Liu, Hongxin,Lv, Gang,et al. Enantioselective Organocatalytic Transfer Hydrogenation of 1,2-Dihydroquinoline through Formation of Aza-o-xylylene[J]. ORGANIC LETTERS,2015,17(17):4125-4127. |
| APA | Li, Guangxun,Liu, Hongxin,Lv, Gang,Wang, Yingwei,Fu, Qingquan,&Tang, Zhuo.(2015).Enantioselective Organocatalytic Transfer Hydrogenation of 1,2-Dihydroquinoline through Formation of Aza-o-xylylene.ORGANIC LETTERS,17(17),4125-4127. |
| MLA | Li, Guangxun,et al."Enantioselective Organocatalytic Transfer Hydrogenation of 1,2-Dihydroquinoline through Formation of Aza-o-xylylene".ORGANIC LETTERS 17.17(2015):4125-4127. |
入库方式： OAI收割
来源：成都生物研究所
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