Group Exchange between Ketones and Carboxylic Acids through Directing Group Assisted Rh-Catalyzed Reorganization of Carbon Skeletons
文献类型：期刊论文
| 作者 | Lei, Zhi-Quan; Pan, Fei; Li, Hu; Li, Yang; Zhang, Xi-Sha; Chen, Kang; Wang, Xin; Li, Yu-Xue; Sun, Jian; Shi, Zhang-Jie |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2015 |
| 卷号 | 137期号:15页码:5012-5020 |
| 关键词 | C-C BOND CROSS-COUPLING REACTIONS ARYL KETONES INTRAMOLECULAR ARYLCYANATION DIRECT ARYLATION METAL INSERTION DOUBLE CLEAVAGE SINGLE BOND ACTIVATION ALKYNES |
| 产权排序 | 1 |
| 通讯作者 | Li, YX (reprint author), Chinese Acad Sci, Key Lab Organometall Chem, Shanghai 200032, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | The Rh(I)-catalyzed direct reorganization of organic frameworks and group exchanges between carboxylic acids and aryl ketones was developed with the assistance of directing group. Biaryls, alkenylarenes, and alkylarenes were produced in high efficiency from aryl ketones and the corresponding carboxylic acids by releasing the other molecule of carboxylic acids and carbon monoxide. A wide range of functional groups were well compatible. The exchanges between two partners were proposed to take place on the Rh-(III) center of key intermediates, supported by experimental mechanistic studies and computational calculations. The transformation unveiled the new catalytic pathway of the group transfer of two organic molecules. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27589]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Lei, Zhi-Quan,Pan, Fei,Li, Hu,et al. Group Exchange between Ketones and Carboxylic Acids through Directing Group Assisted Rh-Catalyzed Reorganization of Carbon Skeletons[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(15):5012-5020. |
| APA | Lei, Zhi-Quan.,Pan, Fei.,Li, Hu.,Li, Yang.,Zhang, Xi-Sha.,...&Shi, Zhang-Jie.(2015).Group Exchange between Ketones and Carboxylic Acids through Directing Group Assisted Rh-Catalyzed Reorganization of Carbon Skeletons.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(15),5012-5020. |
| MLA | Lei, Zhi-Quan,et al."Group Exchange between Ketones and Carboxylic Acids through Directing Group Assisted Rh-Catalyzed Reorganization of Carbon Skeletons".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.15(2015):5012-5020. |
入库方式： OAI收割
来源：成都生物研究所
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