Selective methylation of kaempferol via benzylation and deacetylation of kaempferol acetates
文献类型：期刊论文
| 作者 | Mei, Qinggang; Wang, Chun; Yuan, Weicheng; Zhang, Guolin |
| 刊名 | BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 11页码:288-293 |
| 关键词 | QUERCETIN CYTOTOXICITY ANTIOXIDANT POLYPHENOLS ALKYLATION FLAVONOIDS BINDING |
| 产权排序 | 2 |
| 通讯作者 | Zhang, GL (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | A strategy for selective mono-, di- and tri-O-methylation of kaempferol, predominantly on the basis of selective benzylation and controllable deacetylation of kaempferol acetates, was developed. From the selective deacetylation and benzylation of kaempferol tetraacetate (1), 3,4',5,-tri-O-acetylkaempferol (2) and 7-O-benzyl-3,4'5,-tri-O-acetylkaempferol (8) were obtained, respectively. By controllable deacetylation and followed selective or direct methylation of these two intermediates, eight O-methylated kaempferols were prepared with 51-77% total yields from kaempferol. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Organic |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27598]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Mei, Qinggang,Wang, Chun,Yuan, Weicheng,et al. Selective methylation of kaempferol via benzylation and deacetylation of kaempferol acetates[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,2015,11:288-293. |
| APA | Mei, Qinggang,Wang, Chun,Yuan, Weicheng,&Zhang, Guolin.(2015).Selective methylation of kaempferol via benzylation and deacetylation of kaempferol acetates.BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,11,288-293. |
| MLA | Mei, Qinggang,et al."Selective methylation of kaempferol via benzylation and deacetylation of kaempferol acetates".BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 11(2015):288-293. |
入库方式： OAI收割
来源：成都生物研究所
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