Zn(OTf)(2) promoted rearrangement of 1,2-cyclopropanated sugars with amines: a convenient method for the synthesis of 3-polyhydroxyalkyl-substituted pyrrole derivatives
文献类型：期刊论文
| 作者 | Shen, Xudong; Xia, Jianhui; Liang, Peng; Ma, Xiaofeng; Jiao, Wei; Shao, Huawu |
| 刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 13期号:44页码:10865-10873 |
| 关键词 | DONOR-ACCEPTOR CYCLOPROPANES HIGHLY DIASTEREOSELECTIVE SYNTHESIS DOUBLY ACTIVATED CYCLOPROPANES EFFICIENT SYNTHESIS 3+2 CYCLOADDITION NITRILES STRAIGHTFORWARD CYCLIZATION PRECURSORS ALKALOIDS |
| 产权排序 | 1 |
| 通讯作者 | Shao, HW (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | A rearrangement reaction of 1,2-cyclopropanated sugars with alkylamines or arylamines promoted by Zn(OTf)(2) is described. The method offers a series of 3-polyhydroxyalkyl-substituted pyrrole derivatives with multiple chiral centers in moderate to excellent yields. The epimerization is achieved by inverting the stereochemistry at the free hydroxyl group of the resulting pyrrole, which would give access to many more possible stereoisomers. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Organic |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27600]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Shen, Xudong,Xia, Jianhui,Liang, Peng,et al. Zn(OTf)(2) promoted rearrangement of 1,2-cyclopropanated sugars with amines: a convenient method for the synthesis of 3-polyhydroxyalkyl-substituted pyrrole derivatives[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2015,13(44):10865-10873. |
| APA | Shen, Xudong,Xia, Jianhui,Liang, Peng,Ma, Xiaofeng,Jiao, Wei,&Shao, Huawu.(2015).Zn(OTf)(2) promoted rearrangement of 1,2-cyclopropanated sugars with amines: a convenient method for the synthesis of 3-polyhydroxyalkyl-substituted pyrrole derivatives.ORGANIC & BIOMOLECULAR CHEMISTRY,13(44),10865-10873. |
| MLA | Shen, Xudong,et al."Zn(OTf)(2) promoted rearrangement of 1,2-cyclopropanated sugars with amines: a convenient method for the synthesis of 3-polyhydroxyalkyl-substituted pyrrole derivatives".ORGANIC & BIOMOLECULAR CHEMISTRY 13.44(2015):10865-10873. |
入库方式： OAI收割
来源：成都生物研究所
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