L-Valine derived chiral N-sulfinamides as effective organocatalysts for the asymmetric hydrosilylation of N-alkyl and N-aryl protected ketimines
文献类型：期刊论文
| 作者 | Wang, Chao; Wu, Xinjun; Zhou, Li; Sun, Jan |
| 刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 13期号:2页码:577-582 |
| 关键词 | BASE-CATALYZED HYDROSILYLATION BETA-ENAMINO ESTERS POLYMER-SUPPORTED ORGANOCATALYSTS UNPRECEDENTED SUBSTRATE PROFILE AMINO ACID-DERIVATIVES LEWIS-BASE ENANTIOSELECTIVE REDUCTION AROMATIC KETONES ORGANIC ACTIVATORS TRICHLOROSILANE |
| 产权排序 | 1 |
| 通讯作者 | Wang, C (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China. |
| 合作状况 | 国内 |
| 英文摘要 | L-Valine derived N-sulfinamides have been developed as efficient enantioselective Lewis basic organocatalysts for the asymmetric reduction of N-aryl and N-alkyl ketimines with trichlorosilane. Catalyst 3c afforded up to 99% yield and 96% ee in the reduction of N-alkyl ketimines and up to 98% yield and 98% ee in the reduction of N-aryl ketimines. |
| 学科主题 | Chemistry |
| 类目[WOS] | Chemistry, Organic |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://210.75.237.14/handle/351003/27610]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Wang, Chao,Wu, Xinjun,Zhou, Li,et al. L-Valine derived chiral N-sulfinamides as effective organocatalysts for the asymmetric hydrosilylation of N-alkyl and N-aryl protected ketimines[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2015,13(2):577-582. |
| APA | Wang, Chao,Wu, Xinjun,Zhou, Li,&Sun, Jan.(2015).L-Valine derived chiral N-sulfinamides as effective organocatalysts for the asymmetric hydrosilylation of N-alkyl and N-aryl protected ketimines.ORGANIC & BIOMOLECULAR CHEMISTRY,13(2),577-582. |
| MLA | Wang, Chao,et al."L-Valine derived chiral N-sulfinamides as effective organocatalysts for the asymmetric hydrosilylation of N-alkyl and N-aryl protected ketimines".ORGANIC & BIOMOLECULAR CHEMISTRY 13.2(2015):577-582. |
入库方式： OAI收割
来源：成都生物研究所
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