Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature
文献类型：期刊论文
| 作者 | Wang PX(王培学)1,2 ; Fei YQ(费玉清)1; Li QH(李庆贺)1; Deng YQ(邓友全)1,2
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| 刊名 | Green Chemistry
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| 出版日期 | 2016 |
| 卷号 | 18期号:24页码:6681-6686 |
| ISSN号 | 1463-9262 |
| 通讯作者 | 邓友全 |
| 英文摘要 | A new basic catalyst 3-amino-1,2,4-triazole potassium (KATriz) was prepared, characterized and employed for synthesis of dimethylhexane 1,6-dicarbamate (MHDC) by methoxycarbonylation of 1,6-hexanediamine (HDA) and dimethyl carbonate (DMC). Results showed that KATriz exhibited high catalytic activity and selectivity, 100% HDA conversion with nearly 100% MHDC selectivity that could be obtained at room temperature. The catalyst can be reused for several runs without any deactivation. Besides, the influence of reaction conditions, the structure of amines and the possible catalytic mechanism were also investigated. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 21173240) |
| 语种 | 英语 |
| WOS记录号 | WOS:000389341800029 |
| 源URL | [http://210.77.64.217/handle/362003/20998]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_固体润滑国家重点实验室 |
| 作者单位 | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China 2.Qingdao Center of Resource Chemistry & New Materials, Qingdao, China |
| 推荐引用方式 GB/T 7714 | Wang PX,Fei YQ,Li QH,et al. Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature[J]. Green Chemistry,2016,18(24):6681-6686. |
| APA | Wang PX,Fei YQ,Li QH,&Deng YQ.(2016).Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature.Green Chemistry,18(24),6681-6686. |
| MLA | Wang PX,et al."Effective synthesis of dimethylhexane-1,6-dicarbamate from 1,6-hexanediamine and dimethyl carbonate using 3-amino-1,2,4-triazole potassium as a solid base catalyst at ambient temperature".Green Chemistry 18.24(2016):6681-6686. |
入库方式： OAI收割
来源：兰州化学物理研究所
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