中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Biomimetic Multi-Functional Superamphiphobic FOTS-TiO2 Particles beyond Lotus Leaf

文献类型:期刊论文

作者Chen, Liwei1,2; Guo ZG(郭志光)1,2; Liu WM(刘维民)2
刊名ACS Applied Materials and Interfaces
出版日期2016
卷号8期号:40页码:27188-27198
关键词biomimetic multifunctional superamphiphobic lotus leaf TiO2 anti-icing self-cleaning
ISSN号1944-8244
通讯作者郭志光
英文摘要

It is widely known that natural examples like lotus leaves can only repel room-temperature water but cannot repel hot water and oils. Even though superamphiphobic surfaces composed of re-entrant “mushroom-like” or “T-shaped” structures are promising, they are generally regarded as substrate-dependent and difficult to fabricate, and hence, their practical use on various materials has been limited. Here, we synthesize a flower-like superamphiphobic FOTS-TiO2 powder by solvothermal process and self-assembly functionalization. These structured and functionalized submicron particles can repel the liquids with surface tension as low as 23.8 mN·m–1 (n-decane), which is the lowest among powder samples. With respect to the biomimetic aspect, the surface morphology of FOTS-TiO2 particle is similar to the hierarchical micro/nano-structures of the lotus leaf surface, but it is beyond the lotus leaf for superoleophobic capacity. The difference in the oleophobicity is suggested to be the interplay of quasi-spherical re-entrant structure and perfluorined modification. Because of superior superamphiphobicity of the powder, a facile yet versatile strategy is developed, adhesive-assisted sieve deposition fabrication (AASDF), for preparing superamphiphobic coatings on various substrates. The investigation results pertaining to the water/oil proofing, mechanical durability, self-cleaning, and antifouling performances prove that the FOTS-TiO2 coating is robust and multifunctional, which will enable more opportunities for practical applications. Apart from these general applications, we find that the superamphiphobic FOTS-TiO2 powders when coated on sponge as anti-icing surface have good ice delay and icephobic performances. Furthermore, they can be used to prepare magnetic Fe3O4&FOTS-TiO2 composite particles through liquid marbles, implying significant scientific value.

学科主题材料科学与物理化学
收录类别SCI
资助信息the National Nature Science Foundation of China (Nos. 51522510;51675513);the "Top Hundred Talents" Program of Chinese Academy of Sciences
语种英语
WOS记录号WOS:000385469000087
源URL[http://210.77.64.217/handle/362003/20977]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials and Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan 430062, People’s Republic of China
2.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, People’s Republic of China
推荐引用方式
GB/T 7714
Chen, Liwei,Guo ZG,Liu WM. Biomimetic Multi-Functional Superamphiphobic FOTS-TiO2 Particles beyond Lotus Leaf[J]. ACS Applied Materials and Interfaces,2016,8(40):27188-27198.
APA Chen, Liwei,Guo ZG,&Liu WM.(2016).Biomimetic Multi-Functional Superamphiphobic FOTS-TiO2 Particles beyond Lotus Leaf.ACS Applied Materials and Interfaces,8(40),27188-27198.
MLA Chen, Liwei,et al."Biomimetic Multi-Functional Superamphiphobic FOTS-TiO2 Particles beyond Lotus Leaf".ACS Applied Materials and Interfaces 8.40(2016):27188-27198.

入库方式: OAI收割

来源:兰州化学物理研究所

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