Functionalization and densification of inter-bundle interfaces for improvement in electrical and thermal transport of carbon nanotube fibers
文献类型:期刊论文
作者 | Qiu, Lin1,2; Wang, Xiaotian3; Tang, Dawei1; Zheng, Xinghua1,4; Norris, Pamela M.2; Wen, Dongsheng5; Zhao, Jingna6; Zhang, Xiaohua6; Li, Qingwen6 |
刊名 | CARBON
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出版日期 | 2016-08-01 |
卷号 | 105页码:248-259 |
英文摘要 | Electrical and thermal management in nanodevices by means of carbon nanotube is highly promising. One main challenge toward CNT-based nanoscale electrical and thermal management devices is the development of effective strategies for reducing the bundle-bundle interface resistance. Here we report a novel strategy, based on the densification of CNT bundles and the functionalization of inter-bundle interfaces for effectively enhanced interfacial electrical and thermal transport. The densification is realized by utilizing the local electrostatic cohesion; and the functionalization is realized by the interface-decorated functional groups. Experiments and theoretical analysis demonstrated obviously enhanced interfacial electrical and thermal conductance originates from: (1) local Coulomb electrostatic cohesion between CNT bundles due to surface-induced dipole moments. This effect can promote both electrical and thermal conductance nearly 2.8 times higher than non-functionalized counterpart. (2) Increased interfacial electron transport channels and thermal vibrations due to surface-decorated functional groups. This effect can bring about up to 75% and 95% improvement for thermal and electrical conductance, respectively. This study provides a new methodology for tunable operation of electrical and thermal properties at inter-bundle interfaces and guidance for design of CNT-based electrical and thermal management devices. (C) 2016 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Physical ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Materials Science |
关键词[WOS] | INDUCED TUNNELING CONDUCTION ; RAMAN-SPECTROSCOPY ; GRAPHITE ; YARNS ; HEAT ; NETWORKS ; GRAPHENE ; SOLVENTS ; LONG |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000376607200029 |
源URL | [http://ir.etp.ac.cn/handle/311046/112511] ![]() |
专题 | 工程热物理研究所_中国科学院工程热物理所(论文库)_期刊论文(SCI) |
作者单位 | 1.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China 2.Univ Virginia, Dept Mech & Aerosp Engn, Charlottesville, VA 22904 USA 3.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 4.Univ Calif Riverside, Dept Mech Engn, Riverside, CA 92521 USA 5.Univ Leeds, Sch Chem & Proc Engn, Leeds LS2 9JT, W Yorkshire, England 6.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Key Lab Nanodevices & Applicat, Suzhou 215123, Peoples R China |
推荐引用方式 GB/T 7714 | Qiu, Lin,Wang, Xiaotian,Tang, Dawei,et al. Functionalization and densification of inter-bundle interfaces for improvement in electrical and thermal transport of carbon nanotube fibers[J]. CARBON,2016,105:248-259. |
APA | Qiu, Lin.,Wang, Xiaotian.,Tang, Dawei.,Zheng, Xinghua.,Norris, Pamela M..,...&Li, Qingwen.(2016).Functionalization and densification of inter-bundle interfaces for improvement in electrical and thermal transport of carbon nanotube fibers.CARBON,105,248-259. |
MLA | Qiu, Lin,et al."Functionalization and densification of inter-bundle interfaces for improvement in electrical and thermal transport of carbon nanotube fibers".CARBON 105(2016):248-259. |
入库方式: OAI收割
来源:工程热物理研究所
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