Mechanism of NO Photocatalytic Oxidationon g-C3N4 Was Changed by Pd-QDs Modification
文献类型：期刊论文
| 作者 | Li, YH (Li, Yuhan); Yang, LP (Yang, Liping); Dong, GH (Dong, Guohui); Ho, WK (Ho, Wingkei) |
| 刊名 | MOLECULES
 |
| 出版日期 | 2016 |
| 卷号 | 21期号:1 |
| 关键词 | quantum dot g-C3N4 photocatalytic oxidation NO |
| 英文摘要 | Quantum dot (QD) sensitization can increase the light absorption and electronic transmission of photocatalysts. However, limited studies have been conducted on the photocatalytic activity of photocatalysts after modification by noble metal QDs. In this study, we developed a simple method for fabricating Pd-QD-modified g-C3N4. Results showed that the modification of Pd-QDs can improve the NO photocatalytic oxidation activity of g-C3N4. Moreover, Pd-QD modification changed the NO oxidation mechanism from the synergistic action of h(+) and O-2(-) to the single action of OH. We found that the main reason for the mechanism change was that Pd-QD modification changed the molecular oxygen activation pathway from single-electron reduction to two-electron reduction. This study can not only develop a novel strategy for modifying Pd-QDs on the surface of photocatalysts, but also provides insight into the relationship between Pd-QD modification and the NO photocatalytic oxidation activity of semiconductor photocatalysts. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000369485600027 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4704]  |
| 专题 | 新疆理化技术研究所_环境科学与技术研究室 |
| 作者单位 | 1.Hong Kong Inst Educ, Dept Sci & Environm Studies, Tai Po, Hong Kong, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China 3.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, YH ,Yang, LP ,Dong, GH ,et al. Mechanism of NO Photocatalytic Oxidationon g-C3N4 Was Changed by Pd-QDs Modification[J]. MOLECULES,2016,21(1). |
| APA | Li, YH ,Yang, LP ,Dong, GH ,&Ho, WK .(2016).Mechanism of NO Photocatalytic Oxidationon g-C3N4 Was Changed by Pd-QDs Modification.MOLECULES,21(1). |
| MLA | Li, YH ,et al."Mechanism of NO Photocatalytic Oxidationon g-C3N4 Was Changed by Pd-QDs Modification".MOLECULES 21.1(2016). |
入库方式： OAI收割
来源：新疆理化技术研究所
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