Synthesis and properties of acrylate-acrylic acid-acrylate triblock copolymers with gemini structure by RAFT polymerization
文献类型：期刊论文
| 作者 | Yu, EL (Yu, Erlei); Mamat, X (Mamat, Xamxikamar); Zhi, KK (Zhi, Keke); Zhang, XM (Zhang, Xuemin); Zhang, YG (Zhang, Yagang) ; Eli, W (Eli, Wumanjiang)
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| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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| 出版日期 | 2016 |
| 卷号 | 133期号:7 |
| 关键词 | addition polymerization copolymers micelles molecular recognition radical polymerization |
| 通讯作者 | Zhang, YG |
| 英文摘要 | A class of gemini structure block copolymers with a trithiocarbonate ester spacer group had been synthesized with S, S'-bis (R, R'-dimethylacetic acid) trithiocarbonate as reversible addition fragmentation chain transfer agents and acrylic acid as the second monomer. These triblock copolymers were characterized by H-1 NMR spectroscopy, gel permeation chromatography in terms of their compositions, molecular weights and behaviour at the air-water interface. The results showed that the weight-average molecular weight was larger than theoretical molecular as the acrylate side chain increased. The polymer neutralized by sodium hydroxide solution had low critical micelle concentration which was <10(-2) mol L-1 in water. TEM and DLS showed that it formed a special micelle structure with large pore structure which might lead to low surface tension and critical micelle concentration in water. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000367845800020 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4683]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区精细化工工程技术研究中心 新疆理化技术研究所_资源化学研究室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Xinjiang Inst Engn, Dept Chem & Environm Engn, Urumqi 830091, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, EL ,Mamat, X ,Zhi, KK ,et al. Synthesis and properties of acrylate-acrylic acid-acrylate triblock copolymers with gemini structure by RAFT polymerization[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2016,133(7). |
| APA | Yu, EL ,Mamat, X ,Zhi, KK ,Zhang, XM ,Zhang, YG ,&Eli, W .(2016).Synthesis and properties of acrylate-acrylic acid-acrylate triblock copolymers with gemini structure by RAFT polymerization.JOURNAL OF APPLIED POLYMER SCIENCE,133(7). |
| MLA | Yu, EL ,et al."Synthesis and properties of acrylate-acrylic acid-acrylate triblock copolymers with gemini structure by RAFT polymerization".JOURNAL OF APPLIED POLYMER SCIENCE 133.7(2016). |
入库方式： OAI收割
来源：新疆理化技术研究所
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