Ba-7(BO3)(3)GeO4X (X = Cl, Br): borogermanate halides with rigid GeO4 tetrahedra and flexible XBa6 octahedra
文献类型：期刊论文
| 作者 | Wen, M (Wen, Ming); Lian, ZP (Lian, Zhipeng); Wu, HP (Wu, Hongping); Su, X (Su, Xin); Yan, QF (Yan, Qingfeng); Lu, JJ (Lu, Juanjuan); Yang, ZH (Yang, Zhihua) ; Pan, SL (Pan, Shilie)
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:66页码:53448-53454 |
| 通讯作者 | Wu, HP |
| 英文摘要 | The first borogermanate halides, Ba-7(BO3)(3)GeO4X (X = Cl, Br), have been synthesized using a high temperature solution method. Ba-7(BO3)(3)GeO4X (X = Cl, Br) are isostructural and crystallize in the orthorhombic space group Pbam (no. 55). They feature a Ba-based 3D framework, while isolated GeO4 tetrahedra and BO3 triangles fill in the space created by the framework. Significantly, Ba-7(BO3)(3)GeO4X (X = Cl, Br) possess a similar formula to the borosilicate halides, Ba-7(BO3)(3)SiO4X (X = Cl, Br), but they are not isostructural. An interpretation for the structural transformation between them is demonstrated here, considering rigid GeO4 tetrahedra and flexible XBa6 (X = Cl, Br) octahedra. IR spectroscopy, UV-Vis-NIR diffuse reflectance spectroscopy and first-principles calculations have been carried out on the title compounds. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000356801300036 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4539]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Xinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China;Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, M ,Lian, ZP ,Wu, HP ,et al. Ba-7(BO3)(3)GeO4X (X = Cl, Br): borogermanate halides with rigid GeO4 tetrahedra and flexible XBa6 octahedra[J]. RSC ADVANCES,2015,5(66):53448-53454. |
| APA | Wen, M .,Lian, ZP .,Wu, HP .,Su, X .,Yan, QF .,...&Pan, SL .(2015).Ba-7(BO3)(3)GeO4X (X = Cl, Br): borogermanate halides with rigid GeO4 tetrahedra and flexible XBa6 octahedra.RSC ADVANCES,5(66),53448-53454. |
| MLA | Wen, M ,et al."Ba-7(BO3)(3)GeO4X (X = Cl, Br): borogermanate halides with rigid GeO4 tetrahedra and flexible XBa6 octahedra".RSC ADVANCES 5.66(2015):53448-53454. |
入库方式： OAI收割
来源：新疆理化技术研究所
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