New fluoroborate Cd8B5O15F with two different isolated borate anions prepared by an open high-temperature solution method
文献类型：期刊论文
| 作者 | Yang, Y (Yang, Yun) ; Dong, XY (Dong, Xiaoyu); Pan, SL (Pan, Shilie)
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| 刊名 | DALTON TRANSACTIONS
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| 出版日期 | 2016 |
| 卷号 | 45期号:16页码:7008-7013 |
| 通讯作者 | Pan, SL |
| 英文摘要 | The novel cadmium fluoroborate crystal Cd8B5O15F has been successfully obtained from the reaction of the high-temperature solution method in open air for the first time. An X-ray crystallographic study of the product reveals that Cd8B5O15F crystallizes in the space group Fd (3) over barm. The parameters of the cubic unit cell are a = 13.972(3) angstrom, and Z = 8. The title compound exhibits a complicated three-dimensional (3D) network. And the crystal structure is composed of two isolated borate anions: BO3 and B(O/F)(4). For the B(O/F)(4) group, it consists of the occupancy of F and O with the ratio of 3 : 1. Spectroscopic properties using the IR spectrum, X-ray photoelectron spectroscopy, and Raman spectrum were measured to illustrate this feature. The thermal behavior and UV-Vis-NIR diffuse-reflectance spectrum of Cd8B5O15F are also reported in this work. |
| 收录类别 | SCI |
| WOS记录号 | WOS:000374549100029 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/4701]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Xinjiang Inst Engn, Engn Dept Chem & Environm, 236 Nanchang Rd, Urumqi 830091, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Y ,Dong, XY ,Pan, SL . New fluoroborate Cd8B5O15F with two different isolated borate anions prepared by an open high-temperature solution method[J]. DALTON TRANSACTIONS,2016,45(16):7008-7013. |
| APA | Yang, Y ,Dong, XY ,&Pan, SL .(2016).New fluoroborate Cd8B5O15F with two different isolated borate anions prepared by an open high-temperature solution method.DALTON TRANSACTIONS,45(16),7008-7013. |
| MLA | Yang, Y ,et al."New fluoroborate Cd8B5O15F with two different isolated borate anions prepared by an open high-temperature solution method".DALTON TRANSACTIONS 45.16(2016):7008-7013. |
入库方式： OAI收割
来源：新疆理化技术研究所
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