Microscopic Investigation of Grain Boundaries in Organolead Halide Perovskite Solar Cells
文献类型:期刊论文
作者 | Li, Jiang-Jun; Ma, Jing-Yuan; Ge, Qian-Qing; Hu, Jin-Song; Wang, Dong; Wan, Li-Jun |
刊名 | ACS APPLIED MATERIALS & INTERFACES
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出版日期 | 2015-12-30 |
卷号 | 7期号:51页码:28518-28523 |
关键词 | perovskite solar cells GBs KPFM c-AFM CPD photocurrent |
英文摘要 | Grain boundaries (GBs) play an important role in organic inorganic halide perovskite solar cells, which have generally been recognized as a new class of materials for photovoltaic applications. To definitely understand the electrical structure and behavior of GBs, here we present Kelvin probe force microscopy and conductive atomic force microscopy (cAFM) measurements of both typical and inverted planar organolead halide perovskite solar cells. By comparing the contact potential difference (CPD) of these two devices in the dark and under illumination, we found that a downward band bending exists in GBs that predominantly attract photoinduced electrons. The c-AFM measurements observed that higher photocurrents flow through GBs when a low bias overcomes the barrier created by the band bending, indicating that GBs act as effective charge dissociation interfaces and photocurrent transduction pathways rather than recombination sites. |
收录类别 | SCI |
语种 | 英语 |
源URL | [http://ir.iccas.ac.cn/handle/121111/35799] ![]() |
专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
作者单位 | Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jiang-Jun,Ma, Jing-Yuan,Ge, Qian-Qing,et al. Microscopic Investigation of Grain Boundaries in Organolead Halide Perovskite Solar Cells[J]. ACS APPLIED MATERIALS & INTERFACES,2015,7(51):28518-28523. |
APA | Li, Jiang-Jun,Ma, Jing-Yuan,Ge, Qian-Qing,Hu, Jin-Song,Wang, Dong,&Wan, Li-Jun.(2015).Microscopic Investigation of Grain Boundaries in Organolead Halide Perovskite Solar Cells.ACS APPLIED MATERIALS & INTERFACES,7(51),28518-28523. |
MLA | Li, Jiang-Jun,et al."Microscopic Investigation of Grain Boundaries in Organolead Halide Perovskite Solar Cells".ACS APPLIED MATERIALS & INTERFACES 7.51(2015):28518-28523. |
入库方式: OAI收割
来源:化学研究所
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