Nanocarbon-based TEMPO as stable heterogeneous catalysts for partial oxidation of alcohols
文献类型：期刊论文
| 作者 | Sun, Yongbin; Cao, Changyan; Wei, Fang; Huang, Peipei; Yang, Shuliang; Song, Weiguo |
| 刊名 | SCIENCE BULLETIN
 |
| 出版日期 | 2016-05-01 |
| 卷号 | 61期号:10页码:772-777 |
| 关键词 | Fullerene Hollow sphere TEMPO Heterogeneous catalyst Oxidation of alcohols |
| 英文摘要 | Polymerized fullerene hollow spheres bonded with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) have been successfully synthesized via amination of C-60 with 4-amino-TEMPO in the presence of H2O2, and then cross-linked by 1,6-hexanediamine. The hollow spheres were analyzed by fourier transform infrared spectrometer, electron spin resonance and X-ray photoelectron spectroscopy analysis, which indicated the presence of N-O free radicals in the products. When used as a typical heterogeneous catalyst for selective oxidation of alcohols to the corresponding aldehydes or ketones, it exhibited excellent activities, selectivity and recyclability. This synthesis route is convenient and effective, and may provide a new approach to developing immobilized fullerene based heterogeneous catalysts with high activity and recyclability. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36136]  |
| 专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yongbin,Cao, Changyan,Wei, Fang,et al. Nanocarbon-based TEMPO as stable heterogeneous catalysts for partial oxidation of alcohols[J]. SCIENCE BULLETIN,2016,61(10):772-777. |
| APA | Sun, Yongbin,Cao, Changyan,Wei, Fang,Huang, Peipei,Yang, Shuliang,&Song, Weiguo.(2016).Nanocarbon-based TEMPO as stable heterogeneous catalysts for partial oxidation of alcohols.SCIENCE BULLETIN,61(10),772-777. |
| MLA | Sun, Yongbin,et al."Nanocarbon-based TEMPO as stable heterogeneous catalysts for partial oxidation of alcohols".SCIENCE BULLETIN 61.10(2016):772-777. |
入库方式： OAI收割
来源：化学研究所
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