Concise synthesis of calystegines B-2 and B-3 via intramolecular Nozaki-Hiyama-Kishi reaction
文献类型：期刊论文
| 作者 | Wang, Hong-Yao1,2; Kato, Atsushi3; Kinami, Kyoko3; Li, Yi-Xian1; Fleet, George W. J.4,5; Yu, Chu-Yi1,5 |
| 刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
 |
| 出版日期 | 2016-06-07 |
| 卷号 | 14期号:21页码:4885-4896 |
| 英文摘要 | The key step in the concise syntheses of calystegine B-2 and its C-2 epimer calystegine B-3 was the construction of cycloheptanone 8 via an intramolecular Nozaki-Hiyama-Kishi (NHK) reaction of 9, an aldehyde containing a Z-vinyl iodide. Vinyl iodide 9 was obtained by the Stork olefination of aldehyde 10, derived from carbohydrate starting materials. Calystegines B-2 (3) and B-3 (4) were synthesized from D-xylose and L-arabinose derivatives respectively in 11 steps in excellent overall yields (27% and 19%). |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35570]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, BNLMS, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Toyama Univ, Dept Hosp Pharm, 2630 Sugitani, Toyama 9300194, Japan 4.Univ Oxford, Dept Chem, Chem Res Lab, Mansfield Rd, Oxford OX1 3TA, England 5.Jiangxi Normal Univ, Natl Engn Res Ctr Carbohydrate Synth, Nanchang 330022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Hong-Yao,Kato, Atsushi,Kinami, Kyoko,et al. Concise synthesis of calystegines B-2 and B-3 via intramolecular Nozaki-Hiyama-Kishi reaction[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2016,14(21):4885-4896. |
| APA | Wang, Hong-Yao,Kato, Atsushi,Kinami, Kyoko,Li, Yi-Xian,Fleet, George W. J.,&Yu, Chu-Yi.(2016).Concise synthesis of calystegines B-2 and B-3 via intramolecular Nozaki-Hiyama-Kishi reaction.ORGANIC & BIOMOLECULAR CHEMISTRY,14(21),4885-4896. |
| MLA | Wang, Hong-Yao,et al."Concise synthesis of calystegines B-2 and B-3 via intramolecular Nozaki-Hiyama-Kishi reaction".ORGANIC & BIOMOLECULAR CHEMISTRY 14.21(2016):4885-4896. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。