Synthesis and self-assembly of novel oxacalix[2]arene[2]triazine amphiphiles
文献类型：期刊论文
| 作者 | Xu, Ruibin1,3; Hou, Baoyong1; Wang, Dexian1,3; Wang, Meixiang2 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 59期号:10页码:1306-1310 |
| 关键词 | oxacalix[2]arene[2]triazine heteracalixaromatics amphiphile self-assembly |
| 英文摘要 | Heteracalixaromatics are an emerging generation of macrocyclic host molecules in supramolecular chemistry. As a typical example of heteracalixaromatics, oxacalix[2]arene[2]triazine adopts a shape-persistent 1,3-alternate conformation and can be easily functionalized. Taking it as a platform, a series of oxacalix[2]arene[2]triazine-based amphiphiles bearing long alkyl chains were synthesized through post-macrocyclization functionalization or 3+1 fragment coupling protocols. The self-assembly behavior of these amphiphiles in a mixture of tetrahydrofuran (THF) and water was investigated. Dynamic light scattering (DLS) measurements revealed that the size of the self-assembled aggregates is dependent on the structure of the amphiphiles. The long alkyl chain substituents and/or intermolecular hydrogen bonds were found to promote the self-assembly. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35663]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Ruibin,Hou, Baoyong,Wang, Dexian,et al. Synthesis and self-assembly of novel oxacalix[2]arene[2]triazine amphiphiles[J]. SCIENCE CHINA-CHEMISTRY,2016,59(10):1306-1310. |
| APA | Xu, Ruibin,Hou, Baoyong,Wang, Dexian,&Wang, Meixiang.(2016).Synthesis and self-assembly of novel oxacalix[2]arene[2]triazine amphiphiles.SCIENCE CHINA-CHEMISTRY,59(10),1306-1310. |
| MLA | Xu, Ruibin,et al."Synthesis and self-assembly of novel oxacalix[2]arene[2]triazine amphiphiles".SCIENCE CHINA-CHEMISTRY 59.10(2016):1306-1310. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。