Organocatalytic Enantioselective Reaction of Cyclopent-2-enone-Derived Morita-Baylis-Hillman Alcohols with 4-Hydroxycoumarins
文献类型：期刊论文
| 作者 | Ren, Chuanli1,2; Wei, Feng1; Xuan, Qingqing1; Wang, Dong1; Liu, Li1 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2016-01-07 |
| 卷号 | 358期号:1页码:132-137 |
| 关键词 | Bronsted acids chiral primary amines iminium catalysis pyranocoumarins tandem reactions |
| 英文摘要 | A direct enantioselective reaction of cyclopent-2-enone-derived Morita-Baylis-Hillman alcohols with 4-hydroxycoumarins has been developed under the catalysis of a chiral primary amine derived from cinchonine in combination with a Bronsted acid. The reaction provides pyranocoumarin products with three vicinal chiral carbon centers in highly regio-, diastereo- and enantioselectivities through a tandem allylic alkylation/intramolecular oxa-Michael addition. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35825]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Qingdao Univ Sci & Technol, Sch Polymer Sci & Engn, Qingdao 266042, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Chuanli,Wei, Feng,Xuan, Qingqing,et al. Organocatalytic Enantioselective Reaction of Cyclopent-2-enone-Derived Morita-Baylis-Hillman Alcohols with 4-Hydroxycoumarins[J]. ADVANCED SYNTHESIS & CATALYSIS,2016,358(1):132-137. |
| APA | Ren, Chuanli,Wei, Feng,Xuan, Qingqing,Wang, Dong,&Liu, Li.(2016).Organocatalytic Enantioselective Reaction of Cyclopent-2-enone-Derived Morita-Baylis-Hillman Alcohols with 4-Hydroxycoumarins.ADVANCED SYNTHESIS & CATALYSIS,358(1),132-137. |
| MLA | Ren, Chuanli,et al."Organocatalytic Enantioselective Reaction of Cyclopent-2-enone-Derived Morita-Baylis-Hillman Alcohols with 4-Hydroxycoumarins".ADVANCED SYNTHESIS & CATALYSIS 358.1(2016):132-137. |
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来源：化学研究所
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