Phosphine Oxide-Sc(OTf)(3) Catalyzed Highly Regio- and Enantioselective Bromoaminocyclization of (E)-Cinnamyl Tosylcarbamates. An Approach to a Class of Synthetically Versatile Functionalized Molecules
文献类型：期刊论文
| 作者 | Pan, Hongjie1; Huang, Hu1; Liu, Weigang1; Tian, Hua1; Shi, Yian1,2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2016-03-04 |
| 卷号 | 18期号:5页码:896-899 |
| 英文摘要 | A highly regio- and enantioselective bromoaminocyclization of (E)-cinnamyl tosylcarbamates catalyzed by a chiral phosphine oxide-Sc(OTf)(3) complex is described. A wide variety of optically active aryl 5-bromo-1,3-oxazinan-2-ones can be obtained with high yield and enantioselectivity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35887]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA |
| 推荐引用方式 GB/T 7714 | Pan, Hongjie,Huang, Hu,Liu, Weigang,et al. Phosphine Oxide-Sc(OTf)(3) Catalyzed Highly Regio- and Enantioselective Bromoaminocyclization of (E)-Cinnamyl Tosylcarbamates. An Approach to a Class of Synthetically Versatile Functionalized Molecules[J]. ORGANIC LETTERS,2016,18(5):896-899. |
| APA | Pan, Hongjie,Huang, Hu,Liu, Weigang,Tian, Hua,&Shi, Yian.(2016).Phosphine Oxide-Sc(OTf)(3) Catalyzed Highly Regio- and Enantioselective Bromoaminocyclization of (E)-Cinnamyl Tosylcarbamates. An Approach to a Class of Synthetically Versatile Functionalized Molecules.ORGANIC LETTERS,18(5),896-899. |
| MLA | Pan, Hongjie,et al."Phosphine Oxide-Sc(OTf)(3) Catalyzed Highly Regio- and Enantioselective Bromoaminocyclization of (E)-Cinnamyl Tosylcarbamates. An Approach to a Class of Synthetically Versatile Functionalized Molecules".ORGANIC LETTERS 18.5(2016):896-899. |
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来源：化学研究所
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