Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group
文献类型：期刊论文
| 作者 | Zhang, Geng-Wu1,2; Li, Peng-Fei1; Meng, Zheng1,2; Wang, Han-Xiao1,2; Han, Ying1; Chen, Chuan-Feng1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-04-18 |
| 卷号 | 55期号:17页码:5304-5308 |
| 关键词 | chiral resolution enantioselective recognition host-guest chemistry macrocycles triptycenes |
| 英文摘要 | A new class of chiral macrocyclic arene composed of three chiral 2,6-dihydroxyltriptycene subunits bridged by methylene groups was designed and synthesized. Structural studies showed that the macrocyclic molecule adopts a hex-nut-like structure with a helical chiral cavity and highly fixed conformation. Efficient resolution was achieved through the introduction of chiral auxiliaries to give a couple of enantiopure macrocycles, which exhibited high enantioselectivity towards three pairs of chiral compounds containing a trimethylamino group. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36011]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Geng-Wu,Li, Peng-Fei,Meng, Zheng,et al. Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(17):5304-5308. |
| APA | Zhang, Geng-Wu,Li, Peng-Fei,Meng, Zheng,Wang, Han-Xiao,Han, Ying,&Chen, Chuan-Feng.(2016).Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(17),5304-5308. |
| MLA | Zhang, Geng-Wu,et al."Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.17(2016):5304-5308. |
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来源：化学研究所
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