Iptycene-based stationary phase with three-dimensional aromatic structure for highly selective separation of H-bonding analytes and aromatic isomers
文献类型：期刊论文
| 作者 | Yang, Xiaohong1,2; Han, Ying3; Qi, Meiling1,2; Chen, Chuanfeng3 |
| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2016-05-06 |
| 卷号 | 1445页码:135-139 |
| 关键词 | Iptycene derivative Stationary phase Capillary gas chromatography |
| 英文摘要 | Unique structures and molecular recognition ability endow iptycene derivatives with great potential as stationary phases in chromatography, which, however, has not been explored yet. Herein, we report the first example of utilizing a pentiptycene quinone (PQ) for gas chromatographic (GC) separations. Remarkably, the statically coated capillary column with the stationary phase achieved extremely high column efficiency of 4800 platesim. It exhibited preferential retention and high resolving capability for H-bonding and aromatic analytes and positional isomers, showing advantages over the ordinary polysiloxane phase. Moreover, the fabricated iptycene column showed excellent separation repeatability with RSD values of 0.02-0.06% for intra-day, 0.20-0.35% for inter-day and 3.1-5.5% for between-column, respectively. In conclusion, iptycene derivatives as a new class of stationary phases show promising future for their use in GC separations. (C) 2016 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36092]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ China, Beijing Key Lab Photoelectron Electrophoton Conve, Beijing 100081, Peoples R China 2.Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xiaohong,Han, Ying,Qi, Meiling,et al. Iptycene-based stationary phase with three-dimensional aromatic structure for highly selective separation of H-bonding analytes and aromatic isomers[J]. JOURNAL OF CHROMATOGRAPHY A,2016,1445:135-139. |
| APA | Yang, Xiaohong,Han, Ying,Qi, Meiling,&Chen, Chuanfeng.(2016).Iptycene-based stationary phase with three-dimensional aromatic structure for highly selective separation of H-bonding analytes and aromatic isomers.JOURNAL OF CHROMATOGRAPHY A,1445,135-139. |
| MLA | Yang, Xiaohong,et al."Iptycene-based stationary phase with three-dimensional aromatic structure for highly selective separation of H-bonding analytes and aromatic isomers".JOURNAL OF CHROMATOGRAPHY A 1445(2016):135-139. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。