中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The Importance of End Groups for Solution-Processed Small-Molecule Bulk-Heterojunction Photovoltaic Cells

文献类型:期刊论文

作者Duan, Ruomeng1; Cui, Yong2; Zhao, Yanfei1; Li, Chen1; Chen, Long1; Hou, Jianhui2; Wagner, Manfred1; Baumgarten, Martin1; He, Chang2; Muellen, Klaus1
刊名CHEMSUSCHEM
出版日期2016-05-10
卷号9期号:9页码:973-980
关键词benzodithiophene bulk heterojunction small molecule solar cells thienothiophene
英文摘要End groups in small-molecule photovoltaic materials are important owing to their strong influence on molecular stability, solubility, energy levels, and aggregation behaviors. In this work, a series of donor-acceptor pentads (D-2-A-D-1-A-D-2) were designed and synthesized, aiming to investigate the effect of the end groups on the materials properties and photovoltaic device performance. These molecules share identical central A-D-1-A triads (with benzodithiophene as D-1 and 6-carbonyl-thieno[3,4-b]thiophene as A), but with various D-2 end groups composed of alkyl-substituted thiophene (T), thieno[3,2-b]thiophene (TT), and 2,2'-bithiophene (BT). The results indicate a relationship between conjugated segment/alkyl chain length of the end groups and the photovoltaic performance, which contributes to the evolving molecular design principles for high efficiency organic solar cells.
收录类别SCI
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/35542]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany
2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Zhongguancun North First St 2, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Duan, Ruomeng,Cui, Yong,Zhao, Yanfei,et al. The Importance of End Groups for Solution-Processed Small-Molecule Bulk-Heterojunction Photovoltaic Cells[J]. CHEMSUSCHEM,2016,9(9):973-980.
APA Duan, Ruomeng.,Cui, Yong.,Zhao, Yanfei.,Li, Chen.,Chen, Long.,...&Muellen, Klaus.(2016).The Importance of End Groups for Solution-Processed Small-Molecule Bulk-Heterojunction Photovoltaic Cells.CHEMSUSCHEM,9(9),973-980.
MLA Duan, Ruomeng,et al."The Importance of End Groups for Solution-Processed Small-Molecule Bulk-Heterojunction Photovoltaic Cells".CHEMSUSCHEM 9.9(2016):973-980.

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来源:化学研究所

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