T-shaped and H-shaped polymers constructed from UV-induced strain promoted azide-alkyne cycloaddition reaction
文献类型：期刊论文
| 作者 | Zhu, Wen1; Li, Zi1; Sun, Peng1; Ren, Lixia2; Zhang, Ke1 |
| 刊名 | POLYMER
 |
| 出版日期 | 2016-03-08 |
| 卷号 | 86页码:1-7 |
| 关键词 | Atom transfer radical polymerization H-shaped polymer T-shaped polymer Topological polymer UV-induced strain promoted azide-alkyne cycloaddition |
| 英文摘要 | Topological polymers with T-shaped and H-shaped molecular architecture were built on the combination of atom transfer radical polymerization (ATRP) and UV-induced strain promoted azide-alkyne cycloaddition (SPAAC) reaction. In the presence of a cyclopropenone-masked dibenzocyclooctyne functionalized dibromo ATRP initiator, reactive polystyrene (PS) was synthesized to have a cyclopropenone-masked dibenzocyclooctyne group in the middle of polymer chain. After releasing dibenzocyclooctyne from deprotecting cyclopropenone-masked dibenzocyclooctyne under UV irradiation, T-shaped and H-shaped topological polymers were constructed by reacting PS with mono-end and di-end azide functionalized poly(ethylene oxide) (PEO), respectively, based on the SPAAC reaction. (C) 2016 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35833]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Tianjin Univ, Sch Mat Sci & Engn, 92 Weijin Rd, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Wen,Li, Zi,Sun, Peng,et al. T-shaped and H-shaped polymers constructed from UV-induced strain promoted azide-alkyne cycloaddition reaction[J]. POLYMER,2016,86:1-7. |
| APA | Zhu, Wen,Li, Zi,Sun, Peng,Ren, Lixia,&Zhang, Ke.(2016).T-shaped and H-shaped polymers constructed from UV-induced strain promoted azide-alkyne cycloaddition reaction.POLYMER,86,1-7. |
| MLA | Zhu, Wen,et al."T-shaped and H-shaped polymers constructed from UV-induced strain promoted azide-alkyne cycloaddition reaction".POLYMER 86(2016):1-7. |
入库方式： OAI收割
来源：化学研究所
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