Scalable preparation of cyclic polymers by the ring-closure method assisted by the continuous-flow technique
文献类型：期刊论文
| 作者 | Sun, Peng1; Liu, Jian'an1; Zhang, Zhengbiao2; Zhang, Ke1 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 7期号:12页码:2239-2244 |
| 英文摘要 | The endless molecular topology endows cyclic polymers with fascinating physical properties and applications. As a powerful strategy for the preparation of well-defined cyclic polymers, the current ring-closure methods have an inherent disadvantage of low production efficiency under the classic batch reaction conditions due to the requirement of ultralow reaction concentration for ring-closing linear polymer precursors. Assisted by the continuous-flow technique, we developed an efficient and practical way to ingeniously solve this essential problem and successfully produce cyclic polymers on a large scale by a light-induced ring-closure method for the first time. In addition, due to the large surface-to-volume ratio of the flow reactor, the continuous-flow technique provides the light-induced ring-closing reaction with more uniform light irradiation and transmission, resulting in a significantly increased reaction efficiency compared to that from the classic batch reaction conditions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35935]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Dept Polymer Sci & Engn, Suzhou 215123, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Peng,Liu, Jian'an,Zhang, Zhengbiao,et al. Scalable preparation of cyclic polymers by the ring-closure method assisted by the continuous-flow technique[J]. POLYMER CHEMISTRY,2016,7(12):2239-2244. |
| APA | Sun, Peng,Liu, Jian'an,Zhang, Zhengbiao,&Zhang, Ke.(2016).Scalable preparation of cyclic polymers by the ring-closure method assisted by the continuous-flow technique.POLYMER CHEMISTRY,7(12),2239-2244. |
| MLA | Sun, Peng,et al."Scalable preparation of cyclic polymers by the ring-closure method assisted by the continuous-flow technique".POLYMER CHEMISTRY 7.12(2016):2239-2244. |
入库方式： OAI收割
来源：化学研究所
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