中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Highly linear polyethylenes using the 2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl)-pyridylcobalt chlorides: synthesis, characterization and ethylene polymerization

文献类型:期刊论文

作者Yue, Erlin1,2; Zeng, Yanning1; Zhang, Wenjuan1; Sun, Yang1; Cao, Xiao-Ping2; Sun, Wen-Hua1
刊名SCIENCE CHINA-CHEMISTRY
出版日期2016-10-01
卷号59期号:10页码:1291-1300
关键词cobalt complexes ethylene polymerization highly linear polyethylene unimodal distribution
英文摘要The series of 2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl)pyridine derivatives and their cobalt chlorides (Co1-Co5) were synthesized and fully characterized. The representative complexes Co2 and Co3 were confirmed by single crystal X-ray diffraction analyses, indicating pseudo-square-pyramidal geometry around the cobalt centre. All cobalt complexes, activated with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), exhibited high activities towards ethylene polymerization, and produced polyethylenes with high molecular weight and highly linear feature as well as unimodal distribution.
收录类别SCI
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/35669]  
专题化学研究所_工程塑料实验室
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Yue, Erlin,Zeng, Yanning,Zhang, Wenjuan,et al. Highly linear polyethylenes using the 2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl)-pyridylcobalt chlorides: synthesis, characterization and ethylene polymerization[J]. SCIENCE CHINA-CHEMISTRY,2016,59(10):1291-1300.
APA Yue, Erlin,Zeng, Yanning,Zhang, Wenjuan,Sun, Yang,Cao, Xiao-Ping,&Sun, Wen-Hua.(2016).Highly linear polyethylenes using the 2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl)-pyridylcobalt chlorides: synthesis, characterization and ethylene polymerization.SCIENCE CHINA-CHEMISTRY,59(10),1291-1300.
MLA Yue, Erlin,et al."Highly linear polyethylenes using the 2-(1-(2,4-dibenzhydrylnaphthylimino)ethyl)-6-(1-(arylimino)ethyl)-pyridylcobalt chlorides: synthesis, characterization and ethylene polymerization".SCIENCE CHINA-CHEMISTRY 59.10(2016):1291-1300.

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来源:化学研究所

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