A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols
文献类型：期刊论文
| 作者 | Pan, Bing1; Liu, Bo1; Yue, Erlin2; Liu, Qingbin1; Yang, Xinzheng2; Wang, Zheng1,2; Sun, Wen-Hua2,3
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| 刊名 | ACS CATALYSIS
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| 出版日期 | 2016-02-01 |
| 卷号 | 6期号:2页码:1247-1253 |
| 关键词 | ruthenium catalyst coupling cyclization N-heterocyclic compound AD reaction high efficiency |
| 英文摘要 | The ruthenium complex (8-(2-diphenylphosphinoethyl)aminotrihydroquinolinyl) (carbonyl) (hydrido)ruthenium chloride exhibited extremely high efficiency toward the coupling cyclization of gamma-amino alcohols with secondary alcohols. The corresponding products, pyridine or quinoline derivatives, are obtained in good to high isolated yields. On comparison with literature catalysts whose noble-metal loading with respect to gamma-amino alcohols reached 0.5-1.0 mol % for Ru and a record lowest of 0.04 mol % for It, the current catalyst achieves the same efficiency with a loading of 0.025 mol % for Ru. The mechanism of acceptorless dehydrogenative condensation (ADC) was proposed on the basis of DFT calculations; in addition, the reactive intermediates were determined by GC-MS, NMR, and single-crystal X-ray diffraction. The catalytic process is potentially suitable for industrial applications. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35801]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Bing,Liu, Bo,Yue, Erlin,et al. A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols[J]. ACS CATALYSIS,2016,6(2):1247-1253. |
| APA | Pan, Bing.,Liu, Bo.,Yue, Erlin.,Liu, Qingbin.,Yang, Xinzheng.,...&Sun, Wen-Hua.(2016).A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols.ACS CATALYSIS,6(2),1247-1253. |
| MLA | Pan, Bing,et al."A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of gamma-Amino Alcohols and Secondary Alcohols".ACS CATALYSIS 6.2(2016):1247-1253. |
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来源：化学研究所
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