中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Tuning band alignment by CdS layers using a SILAR method to enhance TiO2/CdS/CdSe quantum-dot solar-cell performance

文献类型:期刊论文

作者Zhang, Bingkai1; Zheng, Jiaxin1; Li, Xiaoning2; Fang, Yanyan2; Wang, Lin-Wang1,3; Lin, Yuan1,2; Pan, Feng1
刊名CHEMICAL COMMUNICATIONS
出版日期2016
卷号52期号:33页码:5706-5709
英文摘要We report tuning band alignment by optimized CdS layers using a SILAR method to achieve the recorded best performance with about 6% PCE in TiO2/CdS/CdSe QDSSCs. Combining experimental and theoretical studies, we find that a better lattices match between CdS and TiO2 assists the growth of CdSe, and the combined effect of charge transfer and surface dipole moment at the TiO2/CdS/CdSe interface shifts the energy levels of TiO2 upward and increases V-oc of the solar cells. More importantly, the band gap of CdS buffer layers is sensitive to the distortion induced by lattice mismatch and numbers of CdS layers. For example, the barrier for charge transfer disappears when there are more than 4 layers of CdS, facilitating the charge injection from CdSe to TiO2.
收录类别SCI
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/36018]  
专题化学研究所_光化学实验室
作者单位1.Peking Univ, Shenzhen Grad Sch, Sch Adv Mat, Shenzhen 518055, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
推荐引用方式
GB/T 7714
Zhang, Bingkai,Zheng, Jiaxin,Li, Xiaoning,et al. Tuning band alignment by CdS layers using a SILAR method to enhance TiO2/CdS/CdSe quantum-dot solar-cell performance[J]. CHEMICAL COMMUNICATIONS,2016,52(33):5706-5709.
APA Zhang, Bingkai.,Zheng, Jiaxin.,Li, Xiaoning.,Fang, Yanyan.,Wang, Lin-Wang.,...&Pan, Feng.(2016).Tuning band alignment by CdS layers using a SILAR method to enhance TiO2/CdS/CdSe quantum-dot solar-cell performance.CHEMICAL COMMUNICATIONS,52(33),5706-5709.
MLA Zhang, Bingkai,et al."Tuning band alignment by CdS layers using a SILAR method to enhance TiO2/CdS/CdSe quantum-dot solar-cell performance".CHEMICAL COMMUNICATIONS 52.33(2016):5706-5709.

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来源:化学研究所

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