Controllable synthesis of a Pd/PdO nanocomposite as a catalyst for hydrogenation of nitroarenes to anilines in water
文献类型：期刊论文
| 作者 | Yang, Fan1; Dong, Sen1; Wang, Chunxia2; Li, Yongfeng1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:58页码:52620-52626 |
| 英文摘要 | A heterogeneous catalytic assembly of the different Pd/PdO ratio nanoparticles supported on oxide carbon nanotubes (OCNTs) can be controllably synthesized by a one-pot gas-liquid interfacial plasma (GLIP) method via adjusting the glow produced parameter. The Pd/PdO nanoparticles have uniform particle size distribution. It is found that the catalysts with different Pd/PdO ratios could affect catalytic activity during the reduction of 4-nitrophenol (4-NP) in water by NaBH4. The best turn over frequency (TOF) value is up to 3000 h(-1), which is much higher than the case only using Pd nanoparticles as catalysts. Moreover, the catalysts allowed hydrogenation of nitroarenes in water by atmospheric pressure H-2, and it displayed remarkable activity toward the hydrogenation of nitroarenes using low Pd loading in good yields. The catalyst can be simply and efficiently used for ten consecutive runs without significant decrease in activity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35524]  |
| 专题 | 化学研究所_活体分析化学实验室 |
| 作者单位 | 1.China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Analyt Chem Living Biosyst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Fan,Dong, Sen,Wang, Chunxia,et al. Controllable synthesis of a Pd/PdO nanocomposite as a catalyst for hydrogenation of nitroarenes to anilines in water[J]. RSC ADVANCES,2016,6(58):52620-52626. |
| APA | Yang, Fan,Dong, Sen,Wang, Chunxia,&Li, Yongfeng.(2016).Controllable synthesis of a Pd/PdO nanocomposite as a catalyst for hydrogenation of nitroarenes to anilines in water.RSC ADVANCES,6(58),52620-52626. |
| MLA | Yang, Fan,et al."Controllable synthesis of a Pd/PdO nanocomposite as a catalyst for hydrogenation of nitroarenes to anilines in water".RSC ADVANCES 6.58(2016):52620-52626. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。