A reversible fluorescent pH-sensing system based on the one-pot synthesis of natural silk fibroin-capped copper nanoclusters
文献类型：期刊论文
| 作者 | Zhang, Guomei1; Xu, Ting1; Du, Huizhi1; Qiao, Yunyun1; Guo, Xiaohong1; Shi, Lihong1; Zhang, Yan1; Shuang, Shaomin1; Dong, Chuan1; Ma, Huimin2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:16页码:3540-3545 |
| 英文摘要 | A one-pot "green'' synthesis of water soluble and pH-responsive natural silk fibroin (SF)-stabilized fluorescent copper nanoclusters (CuNCs) was reported without using any additional reducing agents, and the as-prepared SF@CuNCs exhibited a fluorescence emission at 420 nm with highly stable properties. The reversible pH sensor of the fluorescent SF@CuNCs has been designed based on the obvious fluorescence enhancing properties of CuNCs. Significantly, the SF@CuNCs described here were employed as pH sensors by virtue of the fluorescence intensity of their sensitive response to fluctuating pH in a linear range of 6.08-10.05. Meanwhile, the fluorescence intensity of the SF@CuNCs increased by around 8-fold at high pH values compared with a low pH of 6.08. As expected, the pH sensor was sensitive to different buffer solutions, and also presented a good linear relationship in different buffer solutions. Besides, the ionic strength of the buffers had a slight influence on the pH-responsive behavior and various metal ions showed almost no effects. The proposed method was successfully used to detect the pH of real water samples, thereby indicating its potential practical application. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36041]  |
| 专题 | 化学研究所_活体分析化学实验室 |
| 作者单位 | 1.Shanxi Univ, Ctr Environm Sci & Engn Res, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Analyt Chem Living Biosyst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Guomei,Xu, Ting,Du, Huizhi,et al. A reversible fluorescent pH-sensing system based on the one-pot synthesis of natural silk fibroin-capped copper nanoclusters[J]. JOURNAL OF MATERIALS CHEMISTRY C,2016,4(16):3540-3545. |
| APA | Zhang, Guomei.,Xu, Ting.,Du, Huizhi.,Qiao, Yunyun.,Guo, Xiaohong.,...&Ma, Huimin.(2016).A reversible fluorescent pH-sensing system based on the one-pot synthesis of natural silk fibroin-capped copper nanoclusters.JOURNAL OF MATERIALS CHEMISTRY C,4(16),3540-3545. |
| MLA | Zhang, Guomei,et al."A reversible fluorescent pH-sensing system based on the one-pot synthesis of natural silk fibroin-capped copper nanoclusters".JOURNAL OF MATERIALS CHEMISTRY C 4.16(2016):3540-3545. |
入库方式： OAI收割
来源：化学研究所
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