Biomass-derived gamma-valerolactone as an efficient solvent and catalyst for the transformation of CO2 to formamides
文献类型：期刊论文
| 作者 | Song, Jinliang; Zhou, Baowen; Liu, Huizhen; Xie, Chao; Meng, Qinglei; Zhang, Zhanrong; Han, Buxing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 18期号:14页码:3956-3961 |
| 英文摘要 | Efficient conversion of carbon dioxide (CO2) into valuable chemicals is a very attractive topic. Herein, we conducted the first work on the utilization of biomass-derived gamma-valerolactone (GVL) as the solvent and catalyst for transformation of CO2 with various primary and secondary amines in the presence of phenylsilane (PhSiH3), and the corresponding desired formamides were produced with high yields without any additional catalyst. Systematic studies indicated that the lactone structure of GVL played a key role in the formation of the active silyl formates and the activation of N-H bonds in amines, thus leading to the excellent performance of GVL for the catalytic reactions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35622]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Jinliang,Zhou, Baowen,Liu, Huizhen,et al. Biomass-derived gamma-valerolactone as an efficient solvent and catalyst for the transformation of CO2 to formamides[J]. GREEN CHEMISTRY,2016,18(14):3956-3961. |
| APA | Song, Jinliang.,Zhou, Baowen.,Liu, Huizhen.,Xie, Chao.,Meng, Qinglei.,...&Han, Buxing.(2016).Biomass-derived gamma-valerolactone as an efficient solvent and catalyst for the transformation of CO2 to formamides.GREEN CHEMISTRY,18(14),3956-3961. |
| MLA | Song, Jinliang,et al."Biomass-derived gamma-valerolactone as an efficient solvent and catalyst for the transformation of CO2 to formamides".GREEN CHEMISTRY 18.14(2016):3956-3961. |
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来源：化学研究所
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