Hydrogen from Water over Openly-Structured Graphitic Carbon Nitride Polymer through Photocatalysis
文献类型：期刊论文
| 作者 | Huang, Zhijun; Li, Fengbo; Chen, Bingfeng; Yuan, Guoqing |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2016-03-08 |
| 卷号 | 9期号:5页码:478-484 |
| 关键词 | hydrogen nanostructures nitrides photocatalysis water splitting |
| 英文摘要 | Openly-structured g-C3N4 microspheres (CNMS) are developed through a well-controlled strategy. These materials have unique features of open 3D structure, ordered hierarchical porosity, and improved optical and electronic properties. Hydrogen evolution from water is performed under a 300W Xe lamp with a cut-off filter (>420nm) and Pt nanoparticles are used as the co-catalyst (3.0wt%). The catalyst prepared at 600 degrees C (CNMS-600) has a hydrogen evolution rate (HER) of 392molh(-1) (apparent quantum yield, AQY=6.3%) at 420nm. This value is higher than that of g-C3N4 nanosheets prepared through thermal oxidation, liquid exfoliation, or chemical exfoliation. The HER value is only 27molh(-1) (AQY=0.43%) at 420nm for bulk g-C3N4 from melamine. The evolution of openly-structured CNMS was investigated by TEM, FTIR, and XRD. The improved optical and electronic properties were demonstrated through UV/Vis absorption spectra, valence-band X-ray photoelectron spectroscopy, photoluminescence spectroscopy, electron paramagnetic resonance spectroscopy, and electrochemical impedance spectroscopy. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35921]  |
| 专题 | 化学研究所_绿色印刷实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab New Mat, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Zhijun,Li, Fengbo,Chen, Bingfeng,et al. Hydrogen from Water over Openly-Structured Graphitic Carbon Nitride Polymer through Photocatalysis[J]. CHEMSUSCHEM,2016,9(5):478-484. |
| APA | Huang, Zhijun,Li, Fengbo,Chen, Bingfeng,&Yuan, Guoqing.(2016).Hydrogen from Water over Openly-Structured Graphitic Carbon Nitride Polymer through Photocatalysis.CHEMSUSCHEM,9(5),478-484. |
| MLA | Huang, Zhijun,et al."Hydrogen from Water over Openly-Structured Graphitic Carbon Nitride Polymer through Photocatalysis".CHEMSUSCHEM 9.5(2016):478-484. |
入库方式： OAI收割
来源：化学研究所
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