Cycloaddition of CO2 and epoxide catalyzed by amino- and hydroxyl-rich graphitic carbon nitride
文献类型：期刊论文
| 作者 | Huang, Zhijun; Li, Fengbo; Chen, Bingfeng; Yuan, Guoqing |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:9页码:2942-2948 |
| 英文摘要 | Graphitic carbon nitride (g-C3N4) shows great application potential in the activation of CO2 due to its basic surface functionalities and highly specific electronic properties. Herein, to improve its catalytic performance, g-C3N4 was activated by protonation using H2SO4. The texture, surface chemistry and electronic properties of the as-prepared g-C3N4 were then studied. The synthesis of cyclic carbonate from the cycloaddition of CO2 and epoxide was selected as a model reaction to investigate the catalytic performance. The protonated g-C3N4 exhibited a much higher catalytic activity than the pristine g-C3N4. The generation of terminal amino and hydroxyl groups due to the hydrolysis of g-C3N4 under acidic conditions as well as the higher specific surface area are responsible for the enhanced catalytic performance. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/36091]  |
| 专题 | 化学研究所_绿色印刷实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Green Printing, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Zhijun,Li, Fengbo,Chen, Bingfeng,et al. Cycloaddition of CO2 and epoxide catalyzed by amino- and hydroxyl-rich graphitic carbon nitride[J]. CATALYSIS SCIENCE & TECHNOLOGY,2016,6(9):2942-2948. |
| APA | Huang, Zhijun,Li, Fengbo,Chen, Bingfeng,&Yuan, Guoqing.(2016).Cycloaddition of CO2 and epoxide catalyzed by amino- and hydroxyl-rich graphitic carbon nitride.CATALYSIS SCIENCE & TECHNOLOGY,6(9),2942-2948. |
| MLA | Huang, Zhijun,et al."Cycloaddition of CO2 and epoxide catalyzed by amino- and hydroxyl-rich graphitic carbon nitride".CATALYSIS SCIENCE & TECHNOLOGY 6.9(2016):2942-2948. |
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来源：化学研究所
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