Dependence of poly(3-hydroxybutyrate) crystal modifications on film thickness as revealed by reflection-absorption infrared spectroscopy
文献类型：期刊论文
| 作者 | Pi, Fuwei1,2,3; Wang, Jiping1; Suttiwijitpukdee, Nattaporn4; Chen, Xing5; Zhang, Jianming1 |
| 刊名 | VIBRATIONAL SPECTROSCOPY
 |
| 出版日期 | 2016-09-01 |
| 卷号 | 86页码:35-39 |
| 关键词 | PHB Ultrathin-film Infrared beta-form Biodegradable thermoplastic Nanoscale |
| 英文摘要 | Thickness-dependent ultrathin films of poly(3-hydroxybutyrate) (PHB) were investigated by using infrared reflection-absorption spectroscopy (IRRAS). It was first found that the autogenetic beta-form of PHB could be easily obtained through confining the film thickness under 20 nm at room temperature. Moreover, the interphase of PHB simultaneously exists with the beta-form of PHB in the films with a thickness less than 10 nm. With the film thickness increasing from several nanometers to about 30 nm, the PHB molecules gradually carry out an orientation shift at the b-axis of PHB crystallite; simultaneously, for the alpha-form of PHB a conformational rearrangement probably takes place for the growth of helical crystal unit cells in the ultrathin films. The molecular structures and crystal evolutions at sub-100 nm were explained in detail by analyzing the corresponding IRRAS features. (C) 2016 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35657]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Qingdao Univ Sci & Technol, Minist Educ, Shandong Prov Key Lab Rubber Plast, Key Lab Rubber Plast, Qingdao 266042, Peoples R China 2.Jiangnan Univ, Coll Food Sci, State Key Lab Food Sci & Technol, Wuxi City 214122, Peoples R China 3.Collaborat Innovat Ctr Food Safety & Qual Control, Wuxi, Jiangsu, Peoples R China 4.Kasetsart Univ, Kasetsart Agr & Agroind Prod Improvement Inst KAP, Bangkok 10900, Thailand 5.Chinese Acad Sci ICCAS, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pi, Fuwei,Wang, Jiping,Suttiwijitpukdee, Nattaporn,et al. Dependence of poly(3-hydroxybutyrate) crystal modifications on film thickness as revealed by reflection-absorption infrared spectroscopy[J]. VIBRATIONAL SPECTROSCOPY,2016,86:35-39. |
| APA | Pi, Fuwei,Wang, Jiping,Suttiwijitpukdee, Nattaporn,Chen, Xing,&Zhang, Jianming.(2016).Dependence of poly(3-hydroxybutyrate) crystal modifications on film thickness as revealed by reflection-absorption infrared spectroscopy.VIBRATIONAL SPECTROSCOPY,86,35-39. |
| MLA | Pi, Fuwei,et al."Dependence of poly(3-hydroxybutyrate) crystal modifications on film thickness as revealed by reflection-absorption infrared spectroscopy".VIBRATIONAL SPECTROSCOPY 86(2016):35-39. |
入库方式： OAI收割
来源：化学研究所
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