Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid
文献类型：期刊论文
| 作者 | Xia, Yun-Tao1,2; Sun, Xiao-Tao1,2; Zhang, Ling1,2; Luo, Kai1,2; Wu, Lei1,2,3,4 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2016-11-21 |
| 卷号 | 22期号:48页码:17151-17155 |
| 关键词 | diboronic acid hydrogen atom transfer metal-free nitrogen heterocycles water |
| 英文摘要 | A hydrogenation of N-heterocycles mediated by diboronic acid with water as the hydrogen atom source is reported. A variety of N-heterocycles can be hydrogenated with medium to excellent yields within 10min. Complete deuterium incorporation from stoichiometric D2O onto substrates further exemplifies the H/D atom sources. Mechanism studies reveal that the reduction proceeds with initial 1,2-addition, in which diboronic acid synergistically activates substrates and water via a six-membered ring transition state. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35697]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Yun-Tao,Sun, Xiao-Tao,Zhang, Ling,et al. Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(48):17151-17155. |
| APA | Xia, Yun-Tao,Sun, Xiao-Tao,Zhang, Ling,Luo, Kai,&Wu, Lei.(2016).Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid.CHEMISTRY-A EUROPEAN JOURNAL,22(48),17151-17155. |
| MLA | Xia, Yun-Tao,et al."Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid".CHEMISTRY-A EUROPEAN JOURNAL 22.48(2016):17151-17155. |
入库方式： OAI收割
来源：化学研究所
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