Efficient polymer solar cells based on a copolymer of meta-alkoxy-phenyl-substituted benzodithiophene and thieno[3,4-b]thiophene
文献类型：期刊论文
| 作者 | Li, Wanbin1; Guo, Bing1; Chang, Chunmei1; Guo, Xia1; Zhang, Maojie1; Li, Yongfang1,2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:26页码:10135-10141 |
| 英文摘要 | A new conjugated copolymer, PBTF-OP, based on meta-alkoxyphenyl-substituted benzodithiophene (BDT-m-OP) and 2-ethylhexyl-3- fluorothieno[ 3,4-b] thiophene-2-carboxylate (TT) was designed and synthesized for application as the donormaterial in polymer solar cells (PSCs). PBTF-OP possesses a similar molecular structure to the wellknown polymer PTB7-Th but different conjugated side chains on the BDT unit: meta-alkoxy-phenyl side chains for PBTF-OP and alkylthienyl side chains for PTB7-Th. Compared with PTB7-Th, PBTF-OP exhibits absorption with some blue shifts, while it possesses a deeper HOMO energy level of -5.45 eV and a slightly enhanced hole mobility of 1.25 x 10(-3) cm(2) (V-1 s(-1)) versus a HOMOenergy level of -5.30 eV and a hole mobility of 1.11 x 10(-3) cm(2) (V-1 s(-1)) for PTB7-Th. The PSCs based on PBTF-OP: PC71BM showed a higher power conversion efficiency (PCE) of 9.0% with a higher V-oc of 0.86 V in comparison with a PCE of 8.3% and a V-oc of 0.78 V for PTB7-Th. The results indicate that side chain engineering of BDT-based copolymers is an effective way to improve photovoltaic performance of polymer donors. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35522]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Lab Adv Optoelect Mat, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Wanbin,Guo, Bing,Chang, Chunmei,et al. Efficient polymer solar cells based on a copolymer of meta-alkoxy-phenyl-substituted benzodithiophene and thieno[3,4-b]thiophene[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(26):10135-10141. |
| APA | Li, Wanbin,Guo, Bing,Chang, Chunmei,Guo, Xia,Zhang, Maojie,&Li, Yongfang.(2016).Efficient polymer solar cells based on a copolymer of meta-alkoxy-phenyl-substituted benzodithiophene and thieno[3,4-b]thiophene.JOURNAL OF MATERIALS CHEMISTRY A,4(26),10135-10141. |
| MLA | Li, Wanbin,et al."Efficient polymer solar cells based on a copolymer of meta-alkoxy-phenyl-substituted benzodithiophene and thieno[3,4-b]thiophene".JOURNAL OF MATERIALS CHEMISTRY A 4.26(2016):10135-10141. |
入库方式： OAI收割
来源：化学研究所
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