Optimization of the thermoelectric properties of poly(nickel-ethylenetetrathiolate) synthesized via potentiostatic deposition
文献类型：期刊论文
| 作者 | Sun, Yuanhui1,2; Zhang, Jiajia1,2; Liu, Liyao1,2; Qin, Yunke1,2; Sun, Yimeng1,2; Xu, Wei1,2; Zhu, Daoben1,2 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2016-10-01 |
| 卷号 | 59期号:10页码:1323-1329 |
| 关键词 | coordination polymer organic thermoelectric material potentiostatic deposition |
| 英文摘要 | The coordination polymer poly(nickel-ethylenetetrathiolate) (poly(Ni-ett)), formed by nickel(II) and 1,1,2,2-ethenetetrathiolate (ett), is the most promising N-type organic thermoelectric material ever reported; it is synthesized via potentiostatic deposition, and the effect of different applied potentials on the optimal performance of the polymers is investigated. The optimal thermoelectric property of poly(Ni-ett) synthesized at 0.6 V is remarkably greater than that of the polymers synthesized at 1 and 1.6 V, exhibiting a maximum power factor of up to 131.6 mu W/mK(2) at 360 K. Furthermore, the structure-property correlation of poly(Ni-ett) is also extensively investigated. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses revealed that the larger size of crystalline domains and the higher oxidation state of poly(Ni-ett) synthesized at 0.6 V possibly results in the higher bulk mobility and carrier concentration in the polymer chains, respectively, accounting for the enhanced power factor. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35647]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yuanhui,Zhang, Jiajia,Liu, Liyao,et al. Optimization of the thermoelectric properties of poly(nickel-ethylenetetrathiolate) synthesized via potentiostatic deposition[J]. SCIENCE CHINA-CHEMISTRY,2016,59(10):1323-1329. |
| APA | Sun, Yuanhui.,Zhang, Jiajia.,Liu, Liyao.,Qin, Yunke.,Sun, Yimeng.,...&Zhu, Daoben.(2016).Optimization of the thermoelectric properties of poly(nickel-ethylenetetrathiolate) synthesized via potentiostatic deposition.SCIENCE CHINA-CHEMISTRY,59(10),1323-1329. |
| MLA | Sun, Yuanhui,et al."Optimization of the thermoelectric properties of poly(nickel-ethylenetetrathiolate) synthesized via potentiostatic deposition".SCIENCE CHINA-CHEMISTRY 59.10(2016):1323-1329. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。