Efficient ambipolar transport properties in alternate stacking donor-acceptor complexes: from experiment to theory
文献类型：期刊论文
| 作者 | Qin, Yunke1,2; Cheng, Changli3; Geng, Hua1; Wang, Chao1,2; Hu, Wenping1; Xu, Wei1; Shuai, Zhigang3; Zhu, Daoben1 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2016-05-28 |
| 卷号 | 18期号:20页码:14094-14103 |
| 英文摘要 | Comprehensive investigations of crystal structures, electrical transport properties and theoretical simulations have been performed over a series of sulfur-bridged annulene-based donor-acceptor complexes with an alternate stacking motif. A remarkably high mobility, up to 1.57 cm(2) V-1 s(-1) for holes and 0.47 cm(2) V-1 s(-1) for electrons, was obtained using organic single crystal field-effect transistor devices, demonstrating the efficient ambipolar transport properties. These ambipolar properties arise from the fact that the electronic couplings for both holes and electrons have the same super-exchange nature along the alternate stacking direction. The magnitude of super-exchange coupling depends not only on the intermolecular stacking distance and pattern, but also the energy level alignments between the adjacent donor-acceptor moieties. The concluded transport mechanism and structure-property relationship from this research will provide an important guideline for the future design of organic semiconductors based on donor-acceptor complexes. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35773]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Yunke,Cheng, Changli,Geng, Hua,et al. Efficient ambipolar transport properties in alternate stacking donor-acceptor complexes: from experiment to theory[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2016,18(20):14094-14103. |
| APA | Qin, Yunke.,Cheng, Changli.,Geng, Hua.,Wang, Chao.,Hu, Wenping.,...&Zhu, Daoben.(2016).Efficient ambipolar transport properties in alternate stacking donor-acceptor complexes: from experiment to theory.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,18(20),14094-14103. |
| MLA | Qin, Yunke,et al."Efficient ambipolar transport properties in alternate stacking donor-acceptor complexes: from experiment to theory".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 18.20(2016):14094-14103. |
入库方式： OAI收割
来源：化学研究所
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